C1 Biomass Feedstock Flashcards
source of biomass
- forestry crops&residue
- agriculture crops&residue
- sewage
- animal residue
example biomass
- palm oil empty fruit branch
- sugarcane bagasses
- bamboo
- wooden debris
2D classification of biomass fuel
- biological origin of biomass
- biomass production condition
physiochemical properties
5 properties
- biochemical composition
- moisture content
- mineral matter content
- organic matter ( CHNSO)
- physical properties
biochemical composition type
2 type
- woody feedstock
- non-woody feedstock
woody feedstock main constituent
3 constituent
- cellulose (major)
- hemicellulose
- lignin
cellulose
- much of mechanical strenght of cell wall
- most inner layer in cell wall
hemicellulose
“glue” that connect cellulose & lignin
lignin
- protect from physical and chemical (very hydrophobic) attack
- the most outer layer cell wall
biopolymer (cellulose,hemicellulose&lignin)
proportion biopolymers depend on
- biomass type
- ecosystem type
non woody feedstock constituent
3 constituent
- saccharide(most)
- lipid
- protein
saccharide
- monosaccharide (glucose, galactose, fructose)
- disaccharides (sucrose, lactose, maltose)
- polysaccharides (starch, glycogen)
moisture content types
2 types
it determine applicability of specific biomass
- intrinsic
- extrinsic
intrinsic
plant naturally contain
extrinsic
plant absorb from weather during harvesting and storage
moisture content processing
2 ways
- biochemical
- thermal
biochemical
fermentation & digestion process
favour high moisture
thermal
combustion,gasification,pyrolysis process
only accept low moisture
mineral matter content
- naturally present/ chemically contaminated from industry process
mineral matter content constituent
Si, Ca, K, Na & Mg with small amont of S, P, Fe, Mn & Al
Organic matter (C,H,N,S,O) can be determine through:
2 ways
carbon, hyrogen, nitrogen, sulfur, oxygen
- proximate analysis
- ultimate analysis (C,H,N,S,O)
proximate analysis
- heating biomass in inert atmosphere up to 950°C
- fixed carbon content = mass of residue left after heating biomass
- eg instrument: TGA
ultimate analysis (C,H,N,S,O)
- involve complete & instantaneous oxidation of sample by “flash combustion” then produce NO2, CO2, SO2, H2O
- use specific calibration to determine quantity (C,H,N,S,O)
why determine organic matter important
- N & S =determine enviromental quality. high N & S = unfavorable (produce acidic gas)
- C & H = determine calorific value & biofuel conversion potential
- O =associate with losses and greater CO2 emission
physical properties
physical density
low density make transportation costly
eg, low density ( bulu pelepah) senang terbang bila transport susah and mahal
ways to increase density
2 ways
- physical process (compaction)
- thermal process (torrefaction)
category of technologies for biomass processing
3 categories
- thermochemical processing
- biochemical processing
- physiochemical processing
thermochemical processing
4 types
- combustion
- gasification
- prylolysis
- hydrothermal processsing
biochemical processing
anaerobic digestion
physiochemical processing
2 types
- fermentation
- esterifaction
combustion output
- heat
- steam
- electricity
gasification
- heat
- steam
- electricity
- methane
- hydrogen
pyrolysis
- charcoal/biochar
- biogas
- bio-oil
hydrothermal
- charcoal
- biogas
- bio-oil
anaerobic digestion
- biogas
- digestate
type generation of biofuels
4 generation
- 1st gen (food related source)
- 2nd gen (non-food related source)
- 3rd gen (microalgae)
- 4rt gen (genetically modified microalgae)
1st gen (food related source)
- feedstock of higher saccharide & lipid content
- poses adverse on food security
- require cultivable land for feedstock generation
- -ive impact on environment due to fertilizer&pesticide
- feedstock growth depend largely on environmental factor (temp,humidity etc.)
2nd gen (non-food related source)
- no impact on food security
- no impact on biodiversity
- feedstock growth depend on environmental factor
3rd gen (microalgae)
- no impact on food security
- no impact on biodiversity
- can be cultivate in soil unsuitable for agriculture purpose using waste water
- feedstock can grow on rough condition
- comercial production not yet in place (in research)
4rt gen (genetically modified microalgae)
- no impact on food security
- no impact on biodiversity
- feedstock can grow on rough condition
- aim for overall life cycle of carbon footprint is negative
- technology in early development