C10 - Electrolysis (PAPER 1) Flashcards

1
Q

What is electrolysis

A

the process of using electricity to extract elements from a compound

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2
Q

What is the name of a positive electrode

A

anode

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3
Q

What is the name of a negative electrode

A

cathode

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4
Q

What is an electrolyte

A

liquid or solution that contains ions and so can conduct electricity

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5
Q

Where are metals formed during electrolysis

A

cathode

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6
Q

Where are non-metals formed during electrolysis

A

anode

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7
Q

How can ionic substances be electrolysed

A

by melting or dissolving them, and then passing a direct current through them

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8
Q

What causes ions to move to the electrodes in electrolysis

A

the electric current flowing through the electrolyte

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9
Q

Why can solid ionic compounds not be electrolysed

A

they do not conduct electricity as the ions cannot move

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10
Q

Why are pure elements not always produced in the electrolysis of aqueous solutions

A

Water can also undergo ionisation

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11
Q

What is the half equation of the ionisation of water

A

H2O –> H+ + OH-

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12
Q

When is oxygen gas produced during the electrolysis of a solution
- What is the half-equation for this

A

if no halogen is present
- 4OH- –> O2 + 2H2O + 4e-

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13
Q

What is produced at the anode and cathode during the electrolysis of sodium chloride

A

2Na+ + 2e- –> 2Na (Anode)
2Cl- –> Cl2 + 2e-

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14
Q

When is hydrogen formed during the electrolysis of a solution

A

if the metal is more reactive than hydrogen

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15
Q

What metals are extracted using electrolysis from their compounds

A

ones that are more reactive than carbon

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16
Q

What happens to the metal after electrolysis

A

the metal ions remain in the solution - molten metal

17
Q

What is aluminium oxide mixed with before electrolysis
- what does this do

A
  • cryolite
  • lowers the melting point
18
Q

What is the
- balanced chemical equation
- half equations
of the electrolysis of aluminium oxide

A

2Al2O3 (l) → 4Al (s) + 3O2 (g)

  • Al 3+ + 3e- –> Al
    2O 2- –> O2 + 4e-
19
Q

What are the anodes and cathodes made of in the electrolysis of aluminium oxide

A

anodes - graphite
cathodes - negative carbon lining

20
Q

Why do the anodes in the electrolysis of aluminium oxide need to be replaced

A

they react with the oxygen to make carbon dioxide