Bridging Course 3-4 Flashcards

1
Q

He insisted on a separation of organic and inorganic substances

A

Jons Jacob Berzelius

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2
Q

He produced soaps from various fatty acids and alkalis, thus he was able to demonstrate a chemical change without the ‘vital force’

A

Michel Chevreul

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3
Q

_________made a remarkable discovery because for the first time, an organic compound (urea) was produced from an inorganic source (ammonium cyanate).

A

Friedrich Wohler

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4
Q

He contributed to the downfall of vitalism through the synthesis of acetic acid from carbon disulfide.

A

Hermann Kolbe

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5
Q

Independently and simultaneously, _____________ and ______________ suggested that carbon is tetravalent. The concept on chemical structure greatly influenced the breakthrough for organic chemistry.

A

Friedrich August Kekule
Archibald Scott Couper

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6
Q

He also made significant contributions in chemical structure by stating that carbon is not only tetravalent but also tetrahedral.

A

Jacobus van’t Hoff

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7
Q

He demonstrated the concept of electron dot structures, also known as Lewis structures.

A

Gilbert Newton Lewis

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8
Q

He was responsible for the following important concepts: nature of chemical bond, resonance, hybridization and the molecular orbital theory.

A

Linus Pauling

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9
Q

is a measure of an atom’s attraction for electrons in a bond

A

electronegativity

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10
Q

name the alkyl group
-CH(CH3)CH2CH3
-CH2CH(CH3)2
-C(CH3)3

A

sec-butyl
isobutyl
tert-butyl

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11
Q

fill in the blank

Carboxylic acid
Ester
Amide
_________
_________
_________
Alcohol
Amine
_________
Alkyne
Alkane
_________
_________

A

Carboxylic acid
Ester
Amide
Nitrile*
Aldehyde
*
Ketone*
Alcohol
Amine
Alkene
*
Alkyne
Alkane
Ether*
Alkyl halide
*

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12
Q

give the suffix name and substituent name of
carboxylic acid

A

-oic acid
carboxy

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13
Q

give the suffix name and substituent name of
ester

A

-oate
-alkoxycarbonyl

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14
Q

give the suffix name and substituent name of
amide

A

-amide
amido

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15
Q

give the suffix name and substituent name of
nitrile

A

-nitrile
cyano

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16
Q

give the suffix name and substituent name of
aldehyde

A

-al
-oxo (included in the parent chain) or formyl (not included in the parent chain)

17
Q

give the suffix name and substituent name of
ketone

A

-one
oxo (=O)

18
Q

give the suffix name and substituent name of
alcohol

A

-ol
hydroxy

19
Q

give the suffix name and substituent name of
amine

A

-amine
amino

20
Q

give the suffix name and substituent name of
alkene

A

-ene
alkenyl

21
Q

give the suffix name and substituent name of
alkyne

A

-yne
alkynyl

22
Q

give the suffix name and substituent name of
alkane

A

-ane
alkyl

23
Q

give the substituent name of ether

A

alkoxy

24
Q

give the substituent name of alkyl halide

A

halo

25
Q

how to name spirocyclic compounds

A

spiro[x.y]alkane

26
Q

how to name bridged bicyclic

A

bicyclo[x.y.z]alkane

26
Q

how to name fused bicyclic compounds

A

bicyclo[x.y.0]alkane