Bonding And Structure Flashcards

1
Q

Why are ionic compounds hard?

A

Strong electrostatic attraction between the cations and anions which hold the ions in fixed positions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is the definition of ionic bonding?

A

An ionic bond is the strong electrostatic attraction between anions and cations

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Why do ionic compounds not conduct electricity when solid?

A

The ions are fixed in a giant lattice. They cannot move and carry charge

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What are ionic compounds?

A

Ionic compounds are giant structures with strong electrostatic attraction between cations and anions which are held in place in a fixed structure by these forces

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Why do ionic compounds conduct electricity when molten or in solution?

A

The ionic bonds are broken and the ions are free to move and carry charge

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What is the definition of covalent bonding?

A

The strong electrostatic attraction between a shared pair of electrons and the nuclei of bonded atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Why do ionic compound solids have high melting and boiling points?

A

Strong electrostatic attraction between cations and anions which needs a lot of energy to overcome

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Why does non polar simple covalent not dissolve in water?

A

Water is polar. There is no attraction between polar water molecules and non polar molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Why does polar simple covalent dissolve in water?

A

The delta H+ water is attracted to the delta - of polar molecule and visa versa

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Why do covalent compounds not conduct electricity?

A

No electrons or ions that are free to move

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Why do ionic compounds dissolve in water?

A

Water is polar the slightly positive part of a water molecule attracts anions and the slightly negative part attracts cations

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Why do simple covalent molecules have a low mp and Bp?

A

The intermolecular forces between molecules are weak and not much energy is needed to overcome them

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What is dative covalent bonding?

A

A special form of covalent bonding where both electrons come from only one atom and none come from the other

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

How do you predict the shape of a molecule?

A

Total number of pairs on central atom
How many bonding
How many lone

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What is the bond angle and shape of SF6?

A

90 degrees octahedral

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Why are giant covalent solids with a very high mp?

A

There are many strong covalent bonds throughout the 3D lattice which require a lot of energy to break

17
Q

How much does a lone pair reduce bond angle by?

A

2.5 degrees

18
Q

What is the bond angle and shape of NH3?

A

107 degrees pyramidal

19
Q

Why are metallic bonded items strong?

A

Strong electrostatic attraction between delocalised electrons and positive ions holds the ions in a fixed positions in the lattice

20
Q

What is the bond angle and shape of Bf3?

A

120 degrees and triginal planar

21
Q

Name three giant covalent structures

A

Silicon dioxide diamond graphite

22
Q

What is a permanent dipole dipole?

A

Polar molecules will attract each other

23
Q

What is the bond angle and shape of BeCl2v?

A

180 degrees linear

25
Q

What is the definition of electronegativity?

A

The ability of an atom to attract the bonding pair electrons in a covalent bond

26
Q

What is the two things needed to be a polar molecule?

A

Non symmetrical

Dipoles

27
Q

Where do intermolecular forces occur?

A

Simple covalent

28
Q

Why are metallically bonded items melleable/ductile?

A

When the ions move the delocalised electrons move with them and maintain the electrostatic attraction between them

29
Q

What is ionic bonding between?

A

Metal and non metal ions

29
Q

What is the shape and bond angle of H2O?

A

104.5 v shaped/non linear

30
Q

What molecules does Van Der Waals occur between?

A

Non polar

32
Q

What is the bond angle and shape of Ch4?

A

109.5 degrees tetrahedral

33
Q

How does Van Der Waals forces arise?

A

There is a higher electron density at one side creating an instantaneous dipole
The instantaneous dipole induces a dipole in a neighbouring molecule
The instantaneous dipole and induced dipole attract each other

34
Q

What is the definition of metallic bonding?

A

Strong electrostatic attraction between delocalised electrons and positive cations

35
Q

What molecules does hydrogen bonding occur between?

A

Polar hydrogen atom and F O N

36
Q

How does hydrogen bonding affects the properties of water?

A

Solid ice is less dense than water-hydrogen bonds hold water apart in open lattice structure giving it lower density
Relatively high MP BP-energy is required to break bonds and it takes more energy to break hydrogen bonds as it is the strongest intermolecular force

36
Q

Why do metallically bonded substances have high MP BP

A

Strong electrostatic attraction between delocalised electrons and positive ions requires a lot of energy to overcome

37
Q

Why do metallically bonded items conduct electricity?

A

delocalised electrons can move and carry charge