BIS 103: Photosynthesis II Flashcards
What species makes a proton gradient?
cyt bc1/ cty b6f
Where does water enter from to be broken? N/P?
Lumen - p side
e- progression in photosystem II P680 (first)
2H20 Mn4CaO5 complex Tyrosine free radical Pg680 pheophytin PQa&b
PHeophytin structure
chyl without Mg ion
plastoquinone A/b - which mobile?
B - stuck in thylakoid membrane like Complex 3
Best oxidizing agent
p680 - need e- reduced
analogous to cytc - difference?
plastocyanin- but with Cu
mobile e- carriers of photosynthesis
plastoquinone B, plastocyanin, ferrodoxin
use of Mn4CaO5
has several oxid site -
ground state - loses 4e- -> +4
How does plastoquinone transfer e- to others?
Q cycle - PQH2 drops 2H+, 1e- to self, 1e- to ultimately plastocyanin
plastoquinone structure
9 isoprenes, aromatic for stabil/react (no alcohols)
What’s the ferry between photosystem 1 and 2?
plastocyanin
what enzyme makes NADPH?
Fd:NAD oxidoreductase
What side does plastocyanin reside?
lumen p side
for 1 oxygen,
use _photons
make _NADPH
make _ATP
8 photons
2 NADPH
3 ATP