BioChem Flashcards

1
Q

Which is not a regulatory enzyme of krebs?

A

succinate dehydrogenase (b/c it’s also in ETC)

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2
Q

In conversion of Pyruvate → acetyl CoA via pyruvate dehydrogenase complex, classified as _______ reaction?

A

decarboxylation

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3
Q

Starving, what state are you in?

A

Gluconeogenisis (making carb from non carb)

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4
Q

Which A.A. = aromatic

A

Tryptophan

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5
Q

Which A.A. aids in transportation of fatty acids into mitochondria?

A

methionine (b/c carnirine= lysine & methionine)

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6
Q

What reaction is niacin involved in?

A

Oxidation/reduction

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7
Q

B Vitamin in remetylization of homocysteine

A

B12 (or B9)

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8
Q

What vitamin aids in conversion of ketoacid → amino acid

A

B6 (trans. amination)

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9
Q

Insulin Binding →

A

chromium

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10
Q

What binds to iron & is storage form of iron?

A

Feritin

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11
Q

Good Vit. C=

A

Fruits / Veggies

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12
Q

What fatty acid can body synthesize?

A

palmitic acid

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13
Q

What helps absorb iron?

A

Vitamin C

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14
Q

Glucose + ______ = Lactose

A

Galactose

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15
Q

Which disacharide contains A1-6 linkage

A

isomaltose

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16
Q

Lipoprotein VLDL responsible for transport of _______ ?

VLDL = never dietary
LDL = Leave the liver = Bad
HDL = carries cholesterol
A

Endogenous triglycerides

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17
Q

LDL is responsible for?

A

Endogenous Cholesterol

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18
Q

What doesn’t contribute to cholesterol in obese

A

no answer written down..????

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19
Q

Which is the DNA complimentary strand for:

A

3’ TACGATGC 5’ (at the golf course)

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20
Q

rate limiting enzyme for glycolysis =

A

PPK

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21
Q

comitted step in glycolysis =

A

no answer written down..????

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22
Q

What step in krebs doesn’t produce NADH?

A

Succinate → Fumarate

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23
Q

Where does glycolysis occur?

A

Cytosol

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24
Q

Alpha keto form of which A.A. = intermediate in krebs?

A

Glutamate

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25
What/s formed in succinate → fumerate
FADH 2
26
What contains sulfur & has antibacterial, viral, fungal properties?
Garlic
27
What isn't an example of anaplerotic reaction? | anaplerotic means filling up
Glucose → G6P (Glycolysis)
28
Following is example of a _______ reaction = | 2RCo2H→ (RCO)20+H2O
Dehydration
29
Cereals are low in
Lysine
30
Which complex of electron transport system contains copper?
Cytochrome C Oxidase
31
Which enzyme controlled through product 'inhibitory' allows skeletal muscles cells to accumulate glucose ? inhibitory = rate limiting
PPK (phosphofruscto kinase)
32
Which of these actions occur during a lanine cycle?
Pyruvate is converted to glucose in the liver
33
The malic enzyme catalyzes conversion of malate to pyruvate and provides [which substance used in F.A biosynthesis]?
acetyl CoA
34
Richest source of Vit. E =
Oil (vegetable oil)
35
Hydrolysis of amylopectin by amylase →
Amylose
36
Which hormone enhances activity of glycogen phosphorylase in skeletal muscle?
epinepurine (or Glucagon)
37
Glucose precursors derived from _____?
Amino Acids
38
Principle carb produced by action of alpha-amylase on dietary starch
maltose
39
A.A. derived from proteins are catabolized to products which directly enter the ______ for further oxidation to Co2
tricarboxylic acid cycle (TCA)
40
Enzymes that catylize breakdown of maltose from ______?
Small intestine
41
Which type of F.A is in olive oil?
monounsaturated
42
A lack of lipoprotein lipase results in ______?
elevated chylomicron following fatty meal
43
Phosphate groups of ATP are linked by _____ bonds?
Phosphoanhydride
44
Triacylglycerols transported from intestinal cells to adipose cells within ______?
Chylomicron
45
What hormone ↑ many metabolic processes by ↑
Epinephrine (or Glucagon)
46
Dietary supplementation of therapeutic folic acid maybe be detrimental because..
Can mask B12 deficiency
47
What compound is simple sugar?
dihydroxyacetone
48
What vitamin made by intestinal flora?
Vitamin K
49
What compound catylizes formation of GTP in TCA?
Succinate thiokinase
50
What is characteristic of myoglobulin?
It's a single polypeptide
51
Toxicity of many pesticides result from ________ enzyme inhibition?
irreversible
52
Which of these is C-4 epimere of Glucose?
Galactose [*manose is C-2 epimere to Glucose]
53
Oxidation of what = ketone bodies?
Fatty Acids
54
Good source of Omega 3 =
Salmon
55
Vitamin K = essential to the synthesis of these substances?
Prothrombin
56
Dietary lipids converted to ______ by pancreatic lipase
Lipoprotein
57
Which mineral is required for activity of most glycolytic enzymes?
Sulfur (B vitamin [thiamine, biotin])
58
Glucagon activates which enzyme in plasma membrane of hepatocytes?
Adenyl cyclase
59
Bonding between F.A. & glycerol in a Z-monacyl-Glycerol is best described as what?
Ester linkage
60
When equilibrium is Pos. = 1 then free energy charge is (-)
-1.36
61
In TCA, isocitrate dehydrogenase converts to?
Alphaketoglutanate
62
Which amino acid initiates protein synthesis in humans?
methionine
63
What hormone affects anabolism / catabolism phase of protein metabolism?
Glucocorticoids (cortisol)
64
Disacharide B1→ 4
Lactose
65
Saturation levels of substrate concentration in an enzyme - catylized reaction cause progress..
Neg. cooperativity
66
Tryptophan →
Niacin
67
Coenzyme for oxidative decarboxylation processes
thiamine pyrophosphate (B1) (decarboxylation)
68
Protein complementary allows vegan diet to supply sufficient amounts of ______?
Essential A.A.
69
Enzyme that catylizes peptide bond formation during protein synth. @ ribosome
Peptidyl transferase
70
1 carbon transfers during production of purine & pyrimidines are directly dependent upon?
Pyridoxine
71
Primary function of Vitamin D is to regular absorption and metabolism of which mineral?
Calcium & Phosphorus
72
Cholesterol is not a precursor of what?
Lecithin
73
Which of these characterizes gout?
Purine overproduction
74
Which is a spontaneous reaction?
Gibb's free energy is negative
75
Bile acids contain carboxyl group in side chain that is bound in amide linkage with _____?
Taurine (constituent of bile)
76
Arginase catalyzes conversion of arginine into _____ and urea?
Ornother (ArCo)