Basic Organic Concepts - ALL NOTES Flashcards

1
Q

Define atomic number ?

A

-number of protons in nucleus

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2
Q

Define mass number ?

A

-Number of protons and neutrons in an atom

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3
Q

What is a cation?

A

-A positively charged ion

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4
Q

What is an anion?

A

-A negatively charged ion

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5
Q

What is a mole?

A

-the Avogardro number of particles in a substance

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6
Q

What is Avogadro’s number?

A

-6.022x10^23

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7
Q

What happens to atomic size across period ?

A

-Decreases

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8
Q

What happens to atomic size across group?

A

-Increases

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9
Q

What happens to the number of valence electrons across period?

A

-Increases

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10
Q

What happens to the number of valence electrons across group?

A

-Remains the same

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11
Q

What happens to metallic character across period?

A

-Decreases

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12
Q

What happens to metallic character across group?

A

-Increases

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13
Q

What happens to electron affinity across period?

A

-Increases

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14
Q

What happens to electron affinity across group?

A

-Decreases

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15
Q

What happens to electronegativity across period ?

A

-Increases

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16
Q

What happens to electronegativity across group?

A

-Decreases

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17
Q

What happens to ionisation energy across group?

A

-Decreases

18
Q

What happens to ionisation energy across period?

A

-Increases

19
Q

What is molarity?

A

-The number of moles of solute per litre of solution

20
Q

What are valence electrons?

A

-Electrons in the outermost shell

21
Q

What is valence?

A

-The number of electrons an atom must lose or gain to attain the nearest noble gas

22
Q

How many orbital does the S shell have?

A

-1

23
Q

How many orbitals does the P shell have?

A

-3

24
Q

How many oribitals does the D shell have?

A

-5

25
Q

How many orbitals does the F shell have?

A

-7

26
Q

What is the ground state of electron configuration ?

A

-The lowest energy in an atom

27
Q

What is the excited state electron configuration?

A

-The highest energy in an atom

28
Q

What is the Aufbau principle?

A

-Electrons occupy the orbitals of lowest energy first

29
Q

What is the Pauli Exclusion Principle?

A

-Each atomic orbital can hold a maximum of 2 electrons with opposite spin

30
Q

What is Hund’s rule?

A

-When there are two or more orbitals of the same energy, electrons go on different orbitals rather than pair up

31
Q

What is electronegativity ?

A

-The power of an atom in a molecule to attract electrons to itself

32
Q

What intermolecular forces determine physical properties In molecules ?

A

-Diipole-dipole Waals interactions
-Van Der Waals forces
-Hydrogen bonds

33
Q

What are the Dipole-Dipole interactions?

A

-Interactions between the positive end of one dipole and the negative end on another

34
Q

What are the Van Der Waals forces?

A

-Weak forces of attraction between non-polar molecules

35
Q

What are hydrogen bond interactions?

A

-Attractive forces between hydrogen attached to electronegative atom of one molecule and an electronegative atom of the same or different molecule

36
Q

How can carbon have 4 valence electrons but only 2 available ?

A

-A small amount of energy is used to unpair one of the 2s and move onto 2p to allow large energy output

37
Q

What is sp3 hybridisation of carbon?

A

-Carbon forms 4 single binds eg. CH4

38
Q

What is sp2 hybridisation of carbon?

A

-Carbon forms a double bond eg. C2H4

39
Q

What is sp hybridisation of carbon?

A

-Carbon forms a triple bond or two double bonds to one carbon atom

40
Q

How to fill orbitals ?

A
41
Q

How to draw bond etc?

A