Atomic structure and bonds Flashcards

1
Q

The further the shell is from the nucleus, the energy of the electrons is higher or lower?

A

Higher

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2
Q

Shorthand notation for sodium (NA^11)

a) 1s^2 2s^2 2p^6 3s^1
b) 1s^2 2s^5 2p^6 3s^1
c) 1s^5 2s^2 2p^7 3s^5
d) 1s^2 2s^3 2p^6 3s^7

A

1s^2 2s^2 2p^6 3s^1

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3
Q

Definition of Valency

A

Ability of an atom to enter into chemical combination with other elements

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4
Q

What are the 3 types of primary bonding?

A

Ionic, Covalent and metallic

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5
Q

What are the 2 types of secondary bonding

A

van der waals forces and hydrogen bonding

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6
Q

During ionic bonding Na -> Na^+ does the electron count go up or down?

A

Down

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7
Q

During ionic bonding Cl -> Cl^- does the electron count go up or down?

A

Up

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8
Q

What are the material properties of an ionically bonded material?

A

High melting and boiling points, high hardness, high youngs modulus

Low ductility/ brittle

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9
Q

Describe ionic bonding

A

transfer of electrons from one atom to another creating ions.

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10
Q

Describe covalent bonding

A

Atoms sharing electrons. Electron rings interlinked.

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11
Q

Describe properties of material with only covalent bonds.

A

High young’s modulus but brittle.

high melting and boiling point.

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12
Q

Describe metallic bonding.

A

Sharing of the valence electrons between all the atoms present. electrostatic interaction between electron cloud and metal ions -> binds metal together.

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13
Q

Describe properties of material with metallic bonds.

A

High electrical conductivity.
Good tensile and compressive strength.
High ductility

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14
Q

Are secondary bonds weaker or stronger than primary bonds?

A

Weaker, but have significant affect on material properties.

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15
Q

What is the main difference between primary and secondary bonding?

A

No sharing or transfer of electrons.

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16
Q

Describe van der waals forces.

A

Small forces between one atom’s nucleus and another’s electrons.

17
Q

What affect does temp have on van der waals forces?

A

Higher temprature reduces bond strength.

18
Q

Are hydrogen bonds weaker or stronger than van der waals forces?

A

Stronger.

19
Q

Describe hydrogen bonding.

A

Electrostatic attraction between the small positive and negative charges hold the molecules together.

20
Q

What does the strength of bonds between atoms and molecules affect a material?

A

Melting and boiling points of materials.