aromatic chemistry Flashcards
structure in a benzene ring
compounds with benzene are aromatic they have a planar cyclic structure consigns f a ring of carbon atoms each with a single hydrogen atom sticking out into a flat plane
nature of bonding in a benzene ring
delocalised electron system arise due to overlap of one p oribtal from each carbon atom above and below the plane of ring, electrons are shared evenly so all bond length are the same between the bond
why is benzene more stable than theoretical molecules
the delocalisation of p electrons means there are alternating double and single bonds that is reflected in the hydrogenation of benzene being less exothermic
explain why substitution reactions occur in preference to addition reactions
because lots of energy is needed to disrupt the delocalised system
electrophilic substitution of benzene
electrophilic attack on benzene rings result in substitution , the benzene ring is a region of high electron density which means it attracts electrophiles