API 651: Cathodic Protection of Aboveground Petroleum Storage Tanks Flashcards

1
Q

A concrete tank pad, constructed on a stable, properly prepared subsoil can eliminate what three things? (API 651-14, Section 5.3.3.1)

A

1) eliminating intrusion of groundwater
2) soil-side corrosion, and
3) the need for cathodic protection

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2
Q

What is the most common material used as a pad beneath storage tank bottoms? (API 651-14, Section 5.3.2)

A

Clean sand is the most common material used as a pad beneath aboveground storage tank bottoms.

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3
Q

Why are thick-film, laminated, and chemical- and corrosion-resistant linings primarily installed in tanks? (API 651-14, Section 5.4.4)

A

The purpose of various types of internal tank linings is to mitigate internal corrosion threats and should not be considered as sufficient justification to eliminate the need for external cathodic protection of aboveground storage tank bottoms.

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4
Q

What are the advantages of a sacrificial anode (galvanic) cathodic protection system? (API 651-14, Section 6.2.2)

A

a) no external power supply is required;
b) installation is relatively easy;
c) capital investment is low for small diameter tanks;
d) maintenance costs are minimal;
e) interference problems (stray currents) are rare;
f) less frequent monitoring is required.

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5
Q

Why can secondary containment liners in a dike render a cathodic protection system ineffective? (API 651-14, Section 5.4.3.3)

A

Cathodic protection systems are rendered ineffective when an external liner is installed between the anodes and the tank bottom to be protected, because the external liner acts as a shield to the flow of cathodic protection current necessary for protection.

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6
Q

What are the disadvantages of a sacrificial anode (galvanic) cathodic protection system? (API 651-14, Section 6.2.3)

A

a) driving potential is limited;
b) current output is low;
c) use is limited to low-resistivity soils;
d) not practical for protection of large bare structures;
e) very short life expectancy in low-resistivity soils.

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7
Q

How can impressed current anodes be installed when bedrock is encountered at a shallow depth? (API 651-14, Section 9.3.2.2)

A

Sometimes it is necessary to install an anode in a location where rock is encountered at a shallow depth, or where soil resistivity increases markedly with depth. Such sites can be coped with by a horizontal installation of anodes. A ditch is excavated to whatever depth is practical, and a horizontal column of coke breeze is laid therein, usually square in cross section. The anode is laid horizontally in the center of this column.

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8
Q

What can be done to improve the current distribution to the center of tank bottoms? (API 651-14, Section 9.3.2.3)

A

In some instances, to improve current distribution to the center of the tank, it may be desirable to install anodes in holes which are bored at an angle under the perimeter of the tank bottom or bored horizontally underneath the tank bottom by directional drilling.

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9
Q

When cathodic protection is successfully applied to a tank bottom, the metal surface being protected acts as the __________ of an electrochemical cell.

A

Cathode

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10
Q

How do galvanic cathodic protection systems supply the current required to stop corrosion? (API 651-14, Section 6.2.1)

A

Galvanic systems use a metal more active than the structure to be protected to supply the current required to mitigate corrosion

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11
Q

A sand cushion is placed on top of an old steel tank bottom and a new steel bottom is installed without providing any corrosion prevention measures for the new steel bottom. What will be the likely fate of the new steel bottom? (API 651-14, Section 7.2.4.3)

A

The old bottom forms a shield that collects the cathodic current flowing through the ground and prevents cathodic protection of the new bottom. Unless the anodes are installed between the two steel bottoms (see Figure 8), or the old bottom is removed, electrically isolated, or coated with a nonconductive material, a galvanic cell can develop between the old and new bottom. Industry experience has shown that if a conductive electrolyte exists between bottoms, the current flow and metal loss will be from the new bottom, resulting in premature failure of the new bottom.

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12
Q

What are some advantages and disadvantages of impermeable membrane secondary containment systems? (API 651-14, Section 7.2.5)

A

a) There are several advantages to the installation of an external liner:
b) An external liner provides a means of detecting and containing leaks and preventing ground contamination if leaks occur.
c) An external liner eliminates the natural current flow between the old bottom and the new bottom, thus, reducing the accelerated failure of the new bottom due to galvanic corrosion.
d) An external liner may reduce entry of groundwater into the space between the bottoms
e) Installing an external liner could be disadvantageous for the following reasons.
f) An external liner makes the future addition of cathodic protection difficult.
g) An external liner acts as a basin to contain water or any other electrolyte that might wet the sand between the old and new bottoms, thus, increasing corrosion rates.

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13
Q

Sacrificial anodes intended for use in soil environments are packaged in what kind of backfill? What is the purpose of the backfill? (API 651-14, Section 7.3.5.1.3)

A

Special backfill, consisting of a proper mixture of gypsum, bentonite, and sodium sulfate, promotes anode efficiency, lengthens anode life, and keeps the anode environment moist.

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14
Q

At which electrode of an electrochemical cell does oxidation (corrosion) occur? (API 651-14, Section 3.2)

A

Anode

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15
Q

What is “cathodic protection?” (API 651-14, Section 3.7)

A

A technique to reduce corrosion of a metal surface by making the entire surface the cathode of an electrochemical cell.

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16
Q

What is a “continuity bond?” (API 651-14, Section 3.11)

A

A metallic connection that provides electrical continuity.

17
Q

What is meant by “electrical isolation?” (API 651-14, Section 3.17)

A

The condition of being electrically separated from other metallic structures.

18
Q

What is a “galvanic anode?” (API 651-14, Section 3.25)

A

A metal that, because of its relative position in the galvanic series, provides sacrificial protection to another metal that is more noble, when electrically coupled in an electrolyte. These anodes are the source of current in galvanic or sacrificial cathodic protection.

19
Q

What is meant by “structure-to-electrolyte voltage?” (API 651-14, Section 3.47)

A

The voltage difference between a metallic structure and the electrolyte which is measured with a reference electrode in contact with the electrolyte.

20
Q

What are four major factors that influence the severity of internal corrosion? (API 651-14, Section 4.3)

A

1) conductivity (a function of dissolved solids);
2) suspended solids;
3) pH level;
4) dissolved gases such as CO2, H2S, or O2;
5) sulfate reducing bacteria;
6) temperature.

21
Q

What are four factors that can limit the effectiveness or even preclude the use of cathodic protection on aboveground tank bottoms? (API 651-14, Section 5.1.4)

A

1) tank pads such as concrete;
2) a non-conductive external liner between the tank bottom and anodes (unless anodes are installed between liner and tank bottom);
3) high resistivity soil or coarse/large rock aggregate pads;
4) old aboveground storage tank bottoms left in place when a new bottom is installed.

22
Q

When a native soil pad is to be used beneath an aboveground tank, what characteristics of the soil can be measured to conduct a corrosion analysis of the site? (API 651-14, Section 5.3.7.1)

A

Determination of aggressive ions such as chlorides and sulfates along with measurement of pH and resistivity are helpful for further corrosion analysis. The variety of particle sizes and chemical and electrical differences as discussed in 5.3.1.1and 5.3.2.1 should also be considered in the effectiveness of a cathodic protection system.

23
Q

What are the advantages of an impressed current cathodic protection system? (API 651-14, Section 6.3.2)

A

a) availability of large driving potential;
b) high current output capable of protecting large or small structures;
c) capability of variable current output;
d) applicability to almost any soil resistivity.

24
Q

What are the disadvantages of an impressed current cathodic protection system? (API 651-14, Section 6.3.3)

A

a) possible interference problems (stray currents) on foreign structures;
b) loss of ac power causes loss of protection;
c) higher maintenance and operating costs;
d) higher capital cost for small installations;
e) safety aspects of rectifier location;
f) safety aspects of negative lead connection;
g) more frequent monitoring.

25
Q

What two factors determine the number of sacrificial anodes required to provide cathodic protection for aboveground storage tanks? (API 651-14, Section 7.3.5.1.4)

A

1) total current requirements;

2) the expected individual anode discharge rate in the soil.

26
Q

In impressed current systems, what types of anodes are generally preferred for soil installations? (API 651-14, Section 7.3.5.2.1.2)

A

Graphite, high silicon cast iron, or mixed metal oxide anodes are generally preferred for soil installations.

27
Q

How are current requirement tests for impressed current cathodic protection systems conducted? (API 651-14, Section 7.3.5.2.2.2)

A

Current requirement tests are conducted by forcing a known amount of current from the temporary anode bed through the soil and onto the tank to be protected.

28
Q

What are three generally accepted criteria for determining if adequate cathodic protection has been achieved? (API 651-14, Section 8.2.2)

A

1) A negative (cathodic) potential of at least 850 mV with the cathodic protection current applied.
2) A negative polarized potential of at least 850 mV relative to a CSE.
3) A minimum of 100 mV of cathodic polarization measured between the tank bottom metallic surface and a stable reference electrode contacting the electrolyte.

29
Q

What is the standard method of determining the effectiveness of cathodic protection? (API 651-14, Section 8.3.1)

A

The standard method of determining the effectiveness of cathodic protection on a tank bottom is the tank-top soil potential measurement.

30
Q

How should packaged galvanic anodes be installed? (API 651-14, Section 9.2.1)

A

Packaged galvanic anodes should be backfilled with compacted native soil.

31
Q

Why must the coke breeze backfill around impressed current anodes be correctly installed? (API 651-14, Section 9.3.1.3)

A

The coke breeze shall be correctly installed because loose backfill can result in high resistance and shortened anode life.

32
Q

What is the weak point in all anodes? (API 651-14, Section 9.3.1.3)

A

The cable connection to the anode

33
Q

To what should the negative lead of a cathodic protection rectifier be connected? (API 651-14, Section 9.3.4.3)

A

The negative lead is connected to the structure to be protected and that the positive lead is connected to the anodes.

34
Q

What will happen if the positive and negative output leads from an impressed current cathodic protection rectifier are reversed? (API 651-14, Section 9.3.4.3)

A

If the leads are reversed, with the positive lead mistakenly attached to the tank, the tank bottom will serve as an anode and rapid corrosion failure can result.

35
Q

What can happen if underground wire attached to the positive rectifier terminal is not completely insulated? (API 651-14, Section 9.3.5.1)

A

If not completely insulated, the wire may discharge current (act as an anode), which will result in corrosion of the wire and rapid failure of the cathodic protection installation.

36
Q

What is the recommended frequency of cathodic protection surveys? (API 651-14, Section 11.3.1.2)

A

Annual cathodic protection surveys are recommended to ensure the effectiveness of cathodic protection.

37
Q

What is the recommended frequency for checking sources of impressed current? (API 651-14, Section 11.3.2.2)

A

All sources of impressed current should be checked at intervals not exceeding two months unless specified otherwise by regulation.

38
Q

How long should records related to the effectiveness of cathodic protection be retained? (API 651-14, Section 11.4.7)

A

Records sufficient to demonstrate the need for corrosion control measures should be retained as long as the facility involved remains in service.