Amines (Lecture) Flashcards

1
Q

compounds of nitrogen connected to a CARBONYL GROUP

A

AmiDes

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2
Q

Types of Amines

A

Primary
Secondary
Cyclic
Tertiary

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3
Q

ONE hydrogen atoms of the ammonia mol is replaced by an alkyl or aryl group

A

Primary amines

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4
Q

Methylamine (CH3NH2)
Aniline (C6H5NH2)

A

Primary amines

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5
Q

TWO organic substituents replace the hydrogen atoms of the ammonia molecule forming an amine

A

Secondary amine

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6
Q

Dimethylamine (CH3)2NH
Diphenylamine (C6H5)2NH

A

Secondary amine

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7
Q

all THREE of the hydrogen atoms are replaced by an organic substituent, it could be an aryl oromatic

A

Tertiary amines

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8
Q

Trimethylamine N(CH)3
Ethylendiamineeteraacetic acid EDTA

A

tertiary amines

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9
Q

The secondary or tertiary amines in an aromatic ring structure

A

Cyclic amines

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10
Q

Piperdine (CH2)5NH
Aziridines C2H5N

A

Cyclic amines

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11
Q

Formula of primary amines

A

RNH2

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12
Q

Secondary amines formula

A

R2NH

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13
Q

Tertiary amines formula

A

R3N

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14
Q

They occur in nature, principally as products of the putrefaction of protein material, but they are also present in living tissue

A

Aliphatic amines

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15
Q

Histamine is an example of

A

Cyclic aliphatic amine

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16
Q

A salt is formed by what reaction of amines

A

Addition

17
Q

One of the most important reactions of primary and secondary amines

A

Acylation

18
Q

A hydrogen atom is REPLACED by an acyl group

A

Substitution

19
Q

Amines burns in air, producing water, carbon dioxide and either nitrogen or it’s oxides

A

Oxidation

20
Q

What reaction does Hoffman degration takes place

A

Elimination

21
Q

This is the principal reaction of quarternary ammonium compounds

A

Hoffman degration