Amalgam Flashcards

1
Q

Define amalgam

A

An alloy containing mercury

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2
Q

What is amalgam an alloy of?

A

Mercury

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3
Q

Why is mercury an unusual metal?

A

It is liquid at room temperature s can form cloys at room temp

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4
Q

What is the freezing point of mercury?

A

-39

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5
Q

What is mercury used I?

A

Thermometers
Manometers
Tilt switches
Treatment for STDs

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6
Q

Why is the use of mercury causing contention?

A

As it is a cumulative toxin

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7
Q

Name the most dangerous state of mercury?

A

The organic state and mercury vapour

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8
Q

How can mercury be rendered ‘‘safe’’?`

A

By combining it into an alloy or intermetalic compound

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9
Q

What happens to a dental amalgam once it has been placed the patients mouth?

A

It becomes inert

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10
Q

What is the maximum mercury exposure level according t the WHO?

A

300 mg per week
and/or
air concentration of the vapour of 25 mg/m3

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11
Q

What is the half life of mercury?

A

60 days

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12
Q

Name the components that make up dental amalgam

A
Liquid mercury (Hg)
Powder metal alloy
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13
Q

What is the powder that makes up dental amalgam

A

It is an alloy of the remaining ingredients with the exact composition depending on manufactures preferences.

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14
Q

What reaction occurs when amalgam and mercury mix together?

A

Hg + Ag3Sn -> Ag3Sn + Ag2Hg3 + Sn7Hg

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15
Q

What is the gamma 1 phase fo dental amalgam,?

A

Ag2Hg3

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16
Q

What is the gamma 2 phase for dental amalgam?

A

Sn7Hg

17
Q

What does dental amalgam contain small concentrations of?

A

Copper

18
Q

How much copper may be found in dental amalgam?

A

Below 6% and has little effect n the microstructure

19
Q

What is the gamma 1 phase also referred to as?

A

The matrix as it holds the structure together

20
Q

What has the gamma 2 phase been identified as?

A

Being susceptible to corrosion

21
Q

Why is corrosion bad in relation to dental amalgam ?

A

The products of corrosion tend to distort restorations particularly the mains and this can lead to marginal failure
Also corrosion causes staining of the surrounding tissues

22
Q

What are the remaining products of corrosion made of?

A

They are tin based

23
Q

What do we use to mix amalgam?

A

An amalgamator

24
Q

Why is vigorous mixing necessary?

A

It is required since mercury doesn’t wet the amalgam alloy very well

25
Q

State the 3 forms the amalgam alloy can be shaped into?

A

Lathe cut
Spherical
Mix of both

26
Q

How can we rid of gamma 2?

A

By adding more copper

27
Q

What % by weight of copper is added to the amalgam alloy?

A

12%

28
Q

Wat reaction occurs when copper is adde into a solution of gamma 2alloy?

A

Gamma 1 and Cu6Sn5 are made

29
Q

Where is th copper added in the amalgam?

A

Can be directly incorporated into the amalgam alloy such that the alloy is of 2 intermetalic compounds AgSn and Cu3Sn can be added in s fine powder

30
Q

What is the problem with amalgam?

A
  1. It doesn’t adhere to the tooth
  2. Not aesthetic as silver in colour
  3. May be a need for a therapeutic liner or base material if cavity is large
  4. Poor tensile strength
  5. Send visit required 2 hours later to polish
  6. Forms a corrosion layer
  7. Creep may occur
31
Q

What type of retention occur in amalgam?

A

Entirely mechanical retention

32
Q

As amalgam can only adhere to the tooth mechanically what does th cavity require?

A

An undercut

33
Q

Describe the spherical morphology of amalgam?

A

It is thought to lead to th amalgam flowing better during condensation and so reduction in the amount of Hg needed to make workable material