All Ion Tests Flashcards
What’s the test for functional group sulfate (SO4)
- Acidify with dilute HCl
- Add BaCl2
- White precipitate
What’s the test for functional group carbonate (CO3)
- Add dilute HCl
- Effervescence
- Gas produced turns Limewater cloudy
What’s the test for OH-
- Damp red litmus paper
- Turns from red to blue
What’s the test for the 3 halide ions Cl-, Br-, I-
- Acidify with dilute HNO3
- Add AgNO3
- (Additional test) Add dilute NH3, then conc NH3
What’s the test for NH4+
- Add NaOH
- Heat
- Damp red litmus paper turns from red to blue
What’s the test for Mg2+
In separate test tubes:
- add dilute NaOH —> white ppt
- add dilute H2SO4 —> no visible change
What’s the test for Ca2+
In separate test tubes:
- add dilute NaOH —> white ppt
- add dilute H2SO4 —> slight white ppt
What’s the test for Sr2+
In separate test tubes:
- add dilute NaOH —> no visible change
- add dilute H2SO4 —> white ppt
Whats the test for Ba2+
In separate test tubes:
- add dilute NaOH —> no visible change
- add dilute H2SO4 —> white ppt
What’s the test for 1°, 2°, 3° alcohols
1° & 2°: add acidified potassium dichromate K2Cr2O7 -> orange to green
3° - dichromate remains orange
What’s the general test for all alcohols
add metallic Na -> effervescence (H2 gas made)
What’s the fehlings test for aldehydes
- warm with fehlings solution
- from blue to red ppt
What’s the Tollens test for aldehydes
- warm with tollens reagent
- silver mirror
What’s the test for alkenes
- shake with bromine water
- goes from orange to colourless
What’s the test for carboxylic acids
Add a carbonate eg Na2CO3
- effervescence
- CO2 released which will turn limewater cloudy
How could litmus paper be used to test for pH of oxides
- react with water
- add litmus paper
- if acidic then stays red
- if alkaline then goes from red to blue
Why is acidified BaCl2 solution used to test for sulfate ions
The acid reacts with any carbonate ions present. This removes them, so stopping them giving a false positive result
What is the equation for AgCl and AgBr dissolving in dilute ammonia?
AgCl + 2NH3 -> [Ag(NH3)2]+ + Cl
AgBr + 2NH3 -> [Ag(NH3)2]+ + Cl
How do you test for a Acyl chloride?
- AgNO3 room temp
- steamy white fumes from HCl
- white ppt from AgCl