9.1 Enthalpy Changes Flashcards

1
Q

What is enthalpy?

A

heat energy

stored in a chemical system

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

In an exothermic reaction, is energy overall released or absorbed by the reacting molecules?

A

released

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

In an endothermic reaction, is energy overall released or absorbed by the reacting molecules?

A

absorbed

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

In an exothermic reaction, how does the temperature of the surroundings change?

A

increases

(reactant molecules overall release energy to molecules in surroundings)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

In an endothermic reaction, how does the temperature of the surroundings change?

A

decreases

(reactant molecules overall absorb energy from molecules in surroundings)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

In an exothermic reaction, the enthalpy of the reactants is _____ than the products.

A

greater

(since energy is overall released by the reactant molecules)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

In an endothermic reaction, the enthalpy of the reactants is ____ than the enthalpy of the products.

A

lower

(since reactant molecules overall absorb energy to form products)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Is this reaction exothermic or endothermic?

A

exothermic

(as seen from diagram, enthalpy of products is lower than reactants. therefore overall, energy is released.)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Is this reaction exothermic or endothermic?

A

endothermic

(as seen from diagram, enthalpy of products is greater than reactants. so overall, energy is absorbed.)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Draw an enthalpy profile diagram for a general exothermic reaction, labelling the activation energy & overall energy change.

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

In terms of the relative energies when making/breaking bonds, what makes a reaction exothermic?

A

the energy required to break bonds

is less than

the energy released when bonds are formed.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

In terms of the relative energies when making/breaking bonds, what makes a reaction endothermic?

A

the energy required to break bonds

is greater than

the energy released when bonds are formed

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Is forming bonds exothermic or endothermic?

A

exothermic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Is breaking bonds exothermic or endothermic?

A

endothermic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What is the formula for calculating enthalpy change?

A

ΔH = H(products) - H(reactants)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What is average bond enthalpy?

A

energy required

to break 1 mole of a specified type of bond

in a gaseous molecule

17
Q

What is standard enthalpy change of formation,fH?

A

Enthalpy change when

1 mole of a compound is formed

from its elements

under standard conditions

with all reactants & products in standard states

18
Q

What is standard enthalpy change of combustion, ∆cH?

A

Enthalpy change when

1 mole of a substance completely reacts with O2

under standard conditions

with all reactants & products in standard states

19
Q

What is standard enthalpy change of reaction, ∆rH?

A

Enthalpy change when

reactants react in their molar quantities shown in a balanced equation

under standard conditions

with all reactants & products in their standard states

20
Q

What is standard enthalpy change of neutralisation, ∆neutH?

A

Enthalpy change when

1 mole of H2O is formed from an acid & base

under standard conditions

with reactants & products under standard states

21
Q

What is activation energy, Ea?

A

minimum energy required

to start a reaction

by breaking bonds

22
Q

What does a higher activation energy mean in terms of the rate of reaction?

A

slower rate of reaction

more energy required

so molecules reach activation energy less frequently

23
Q

What does a lower activation energy mean in terms of the rate of reaction?

A

faster rate of reaction

less energy required

therefore molecules reach activation energy more frequently

24
Q

What are standard conditions?

A

PRESSURE: 100kPa

TEMPERATURE: 298K/25°C

CONCENTRATION: 1moldm3

25
Q

How do you convert from kelvin to celsius?

A

add 273