3.5 Lipids Flashcards

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1
Q

What elements do lipids contain?

A

Carbon, Hydrogen and Oxygen

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2
Q

What are lipids commonly known as?

A

Fats and oils.

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3
Q

Are lipids polar or non-polar?

A

Non-polar, the electrons in outer orbitals are evenly distributed

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4
Q

What are lipids built from?

A

Repeating monomers

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5
Q

Are lipids macro or micromolecules?

A

Macromolecules; they are large complex molecules

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6
Q

What is the structure of a triglyceride?

A

One glycerol molecules combined with 3 fatty acids (fatty acids are either all identical or all different)

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7
Q

What functional group do fatty acids belong to?

A

Carboxyl group (-COOH)

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8
Q

Describe the structure of a fatty acid.

A

A hydrocarbon attached to the carboxyl functional group.

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9
Q

Describe the general formula for a fatty acid.

A

RCOOH (Where R is the variable number of carbon and hydrogen atoms)

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10
Q

What do both glycerol and fatty acids contain?

A

Hydroxyl groups (OH)

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11
Q

How does a triglyceride form?

A

The hydroxyl groups of the fatty acids and the glycerol interact in a condensation reaction, formation 3 water molecules and an ester bond between the fatty acids and glycerol molecule.

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12
Q

What is the formula for an ester bond?

A

RCOOR

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13
Q

What kind of reaction is required to break down a triglyceride?

A

A hydrolysis reaction. The three water molecules produced in the condensation reaction need to be supplied back.

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14
Q

What makes a fatty acid saturated, and why?

A

If they have no double bonds between the carbon atoms, because all teh carbon atoms have formed the maximum number of bonds with hydrogen atoms (they are saturated with hydrogen bonds)

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15
Q

What is the name for if there is one double bond in a fatty acid?

A

Monounsaturated

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16
Q

What is the name for if there are two or more double bonds in a fatty acid?

A

Polyunsaturated

17
Q

Why are saturated fatty acids liquids at room temperature?

A

Because the presence of double bonds causes the molecule to bend, so they cannot pack so closely together.

18
Q

What is the general formla for a saturated fatty acid?

A

CnH2n+1 COOH

19
Q

Why are lipids long-term energy stores?

A

Because when fats/oils are hydrolysed, a large amount of energy is released (because the bonds between carbon and hydrogen in the fatty aids contain large amounts of energy).

20
Q

Describe the structure of a phospholipid.

A

2 fatty acids are bonded to a glycerol molecule. This glycerol molecule is attached to a phosphate group

21
Q

What is a phosphate group?

A

The same as a phosphate ion. PO4 (3-)

22
Q

What are the two key sections of a phospholipid?

A

Hydrophobic tails (two fatty acids), hydrophilic head (the glycerol and phosphate group)

23
Q

Is phosphate polar or non-polar?

A

Polar (all ions are polar)

24
Q

Is the hydrophilic head of a phospholipid charged?

A

Yes, negatively charged

25
Q

Are the hydrophobic tails of a phospholipid charged?

A

No

26
Q

Describe what happens to a phospholipid when in water.

A

-The hydrophilic head will interact and dissolve in the water
-Hydrophobic fatty acid tails will stick out of the water
-Phospholipids form a monolayer on the surface of the layer
-Phospholipids are insoluble in water

27
Q

What is the name of the structure that phospholipids form when in an aqueous environment?

A

Two-layered sheet formation (bilayer)

28
Q

Describe the bilayer that phospholipids form when in an aqueous solution.

A

Hydrophobic tails point towards the centre of the sheet, protected from the water by hydrophilic heads

29
Q

Why do phospholipids play a key role in forming cell membranes?

A

Because of the bilayer arrangement that they form, and because they can therefore separate an aqueous environment from the aqueous cytosol within cells.

30
Q

What chemical do you use to test for lipids?

A

Ethanol

31
Q

Describe the method for testing for lipids.

A

1) If testing solid food, grind up the food using a pestle or mortar
2) Add a solvent, like ethanol, to the food sample
3) Place a bung in the test tube and shake thoroughly so that any lipid will dissolve in the solvent
4) Decant the lipid/solvent mixture into a test tube of distilled water
5) The presence of a white emulsion (cloudy) indicates the presence of a starch
6) The degree of cloudiness indicates the amount of lipid present

32
Q

What is a sterol?

A

A type of alcohol

33
Q

Describe the two ends on a sterol.

A

One hydroxyl, polar, hydrophilic end and one non-polar, hydrophobic end

34
Q

What is an important use of cholesterol?

A

Used in the structure of cell membranes, to add stability and regulate their fluidity, by keeping the membrane fluid at a low temperature.

35
Q

Describe the relationship between cholesterol and phospholipids in the cell membrane

A

The hydrophilic ened of the cholesterol molecule is attracted to the hydrophilic heads of the phospholipid.

36
Q

Where does the body manufacture cholesterol?

A

In the liver and intestines

37
Q

What are the biological roles of lipids that they have due to their non-polar nature?

A

-Membrane formation (formation of hydrophobic barriers)
-Hormone production
-Electrical insulation necessary for impulse transmission
-Waterproofing (eg in bird’s feathers)
-Buoyancy for aquatic animals
-Cushioning to protect vital organs
-Thermal insulation to reduce heat loss.