3.3.3: Addition polymers Flashcards
Polymers
Long chain molecules formed when lots of small molecules (monomers) join together
Types of polymers
2
natural or synthetic
Example of a natural polymer
DNA
Example of a synthetic polymer
Polythene
Addition polymers
The double bonds in alkenes open up and join together to make long chains called polymers.
Addition polymerisation
What does n stand for
repeating units
Substituted alkene
An alkene where one of the hydrogen atoms has been swapped for another atom or group
Properties of polymers
saturated?
Alkenes are unsaturated but become saturated when polymers as there are only single bonds in the carbon chin and the double bonds open up
Properties of polymers
polarity?
The main carbon chain in alkenes is usually non-polar
Properties of addition polymers
reactivity?
v unreactive due to saturation and non-polar
Stronger and more rigid polymers
Longer chains with less branches due to stronger intermolcular forces
PVC
poly(chloroethene)
an addition polymer formed from chloroethene monomers
Plasticisers
Chemicals that make polymers bendier
How do plasticisers work?
The molecules get between the polymer chains and push them apart which reduces the strength of intermolecular forces between the chains which makes them slide around more = more flexible
Uses of plasticised PVC
3
electrical cable insulation
flooring tiles
clothing