3.14 - Organic Synthesis Flashcards
What compounds take part in hydrolysis?
Esters Polyesters Polyamides Alkenes Halogenoalkanes
What compounds take part in Acid/Base Hydrolysis?
Esters
Polyesters
Polyamides
What compound requires Alkaline hydrolysis to form an Alcohol?
Halogenoalkane
What reactions require an ethanol solvent?
Halogenoalkane |> Primary amine
Halogenoalkane |> Nitrile
Halogenoalkane |> Alkene
What reactions⁺ require KCN followed by H⁺?
Forming Hydroxynitriles
What reactions require H₂SO₄?
Alcohol |> Ester
Carboxylic Acid |> Ester
Alcohol |> Alkene
Condition for Nucleophilic Addition-Elimination?
Room Temp
Condition for NaBH₄?
Aqueous, Room Temp
Condition for Nucleophilic Substitution?
Heat
Reflux if KCN
Condition for Electrophilic Addition?
Room Temp
Reagents & Conditions: Nitrile |> Amine
H₂, Ni Catalyst
High Temp & Pressure
Reagents & Conditions: Alkene |> Alcohol
Steam & H₃PO₄ Catalyst
300°C, 60 atm
Reagents & Conditions: Nitration of Benzene
conc H₂SO₄ & conc HNO₃
50°C
Reagents & Conditions: Reduction of Aminobenzene
Tin, conc HCl
Reflux
Reagents & Conditions: Acylation of Benzene
RCOCl, AlCl₃
Reflux