3.1.2 Carbohydrates Flashcards
what are monosaccharides?
the monomers from which carbohydrates are made
what are three common monosaccharides?
- glucose
- fructose
- galactose
a condensation reaction between two monosaccharides forms a ___ bond?
glycosidic
the condensation of two monosaccharides forms a…
disaccharide
glucose + glucose –>
maltose
glucose + fructose –>
sucrose
glucose + galactose –>
lactose
what is an isomer?
a molecule with the same molecular formula but a different structure
what are the two isomers of glucose?
α-glucose and β-glucose
what is the difference between α-glucose and β-glucose?
- in α-glucose the OH group bonded to carbon 1 is below the ring
- in β-glucose the OH group bonded to carbon 1 is above the ring
where is glycogen found?
animal cells (especially liver and muscle cells)
where is starch found?
plant cells
where is cellulose found?
the cell wall of plant cells
what is the basic structure of glycogen?
- polysaccharide of α-glucose
- branched structure due to 1,6 glycosidic bonds
what is the basic structure of starch?
- polysaccharide of α-glucose
- amylose has a long unbranched structure which forms a coiled / compact shape
- amylopectin has a branched structure due to 1,6 glycosidic bonds
what is the basic structure of cellulose?
- polysaccharide of β-glucose
- has long and straight chains
- contains lots of hydrogen bonds between straight chains which create microfibrils
explain the structure of cellulose monomers compared to starch monomers
- starch formed from α-glucose but cellulose β-glucose monomers
- so position of hydrogen and hydroxyl groups on carbon atom 1 inverted
what is the basic function of glycogen?
is an energy store
what is the basic function of starch?
is an energy store
what is the basic structure of cellulose?
acts as structural support
how does the structure of glycogen relate to its function?
- branched structure provides a large SA so that it can be quickly hydrolysed by enzymes to release glucose for respiration
- is coiled in shape so can fit many molecules in small area
- is insoluble so has does not affect water potential of cell
how does the structure of starch relate to its function?
- amylopectin’s branched structure provides a large SA so that it can be quickly hydrolysed by enzymes to release glucose for respiration
- amylose is coiled in shape so can fit many molecules in small area
- is insoluble so has does not affect water potential of cell
- large molecule so it cannot leave the cell
how does the structure of cellulose relate to its function?
microfibrils provide strength to the cell wall
what is the food test for reducing sugars?
- add Benedict’s solution and heat in water bath
- if sugar is present, colour change from blue to green / yellow / red
how can you get quantitative data for reducing sugars in a food sample
- filter and dry the precipitate, find the mass
- remove the precipitate and use a colorimeter to measure the absorbance of the remaining Benedict’s solution
what is the food test for non-reducing sugars?
- heat with acid and neutralise
- heat with Benedict’s solution
- red colour if non-reducing sugar is present
what is the food test for starch?
- add iodine / potassium iodide
- colour change to blue / black