3.1 Flashcards
what is the trend in properties repeated across a period.
Periodicity
energy levels in orbitals
within the sub shell energies increase with d having the most
group 2 elements (properties)
Have reasonably high melting and boiling points.
All light metals with low density.
Form colourless (white) compounds
Reactions of group two elements and oxygen
The group two elements react vigorously with oxygen (redox reaction)
Reaction of group two and water
All group two elements apart from beryllium react to form hydroxides.
The general formula is M(OH)2
Hydrogen gas is formed and moving down the group they react more.
solubility down group 2
increases
alkalinity down group 2
increases
calcium hydroxide uses
used by farmers and gardeners to reduce the acidity in soil
use for magnesium hydroxide
neutralising the excess acid and produces salt and water
The halogen properties
Have low melting and boiling points
Exist as diatomic molecules
Trend in boiling points of group 7
The boiling point increases and it goes from gas to liquid to solid.
this is due to the fact that each element has an extra shell of electrons which leads to more temporary dipole dipole bonds
The reactivity and oxidising power down group 7.
This decreases due to:
the atomic radius increasing (nuclear pull is further away from incoming electrons)
the shielding increases
what are the three things effecting ionisation energies.
Nuclear charge- the more protons there are in the nucleus, the more positively charged the nucleus is and the stronger the attraction for the electrons.
Atomic radius- Attraction falls off very rapidly with distance. An electron close to the nucleus will be much more strongly attracted to one further away.
Shielding- As the number of electrons between the outer electrons and the nucleus increases the outer electrons feel less attraction towards the nuclear charge-.
ionisation energy trend down a group
The ionisation energies fall. (larger atomic radius, more shielding) this counteracts the increased nuclear charge- increasing
ionisation energy across a period(general trend)
As you move across a period the general trend is that they increase (due to more nuclear charge and smaller atomic radius)