3.1 Flashcards

1
Q

what is the trend in properties repeated across a period.

A

Periodicity

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2
Q

energy levels in orbitals

A

within the sub shell energies increase with d having the most

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3
Q

group 2 elements (properties)

A

Have reasonably high melting and boiling points.

All light metals with low density.

Form colourless (white) compounds

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4
Q

Reactions of group two elements and oxygen

A

The group two elements react vigorously with oxygen (redox reaction)

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5
Q

Reaction of group two and water

A

All group two elements apart from beryllium react to form hydroxides.

The general formula is M(OH)2

Hydrogen gas is formed and moving down the group they react more.

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6
Q

solubility down group 2

A

increases

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7
Q

alkalinity down group 2

A

increases

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8
Q

calcium hydroxide uses

A

used by farmers and gardeners to reduce the acidity in soil

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9
Q

use for magnesium hydroxide

A

neutralising the excess acid and produces salt and water

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10
Q

The halogen properties

A

Have low melting and boiling points

Exist as diatomic molecules

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11
Q

Trend in boiling points of group 7

A

The boiling point increases and it goes from gas to liquid to solid.

this is due to the fact that each element has an extra shell of electrons which leads to more temporary dipole dipole bonds

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12
Q

The reactivity and oxidising power down group 7.

A

This decreases due to:

the atomic radius increasing (nuclear pull is further away from incoming electrons)

the shielding increases

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13
Q

what are the three things effecting ionisation energies.

A

Nuclear charge- the more protons there are in the nucleus, the more positively charged the nucleus is and the stronger the attraction for the electrons.

Atomic radius- Attraction falls off very rapidly with distance. An electron close to the nucleus will be much more strongly attracted to one further away.

Shielding- As the number of electrons between the outer electrons and the nucleus increases the outer electrons feel less attraction towards the nuclear charge-.

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14
Q

ionisation energy trend down a group

A

The ionisation energies fall. (larger atomic radius, more shielding) this counteracts the increased nuclear charge- increasing

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15
Q

ionisation energy across a period(general trend)

A

As you move across a period the general trend is that they increase (due to more nuclear charge and smaller atomic radius)

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16
Q

ionisation energy between group 2 and 3

A

There is a slight dip as the outer electron in group 3 is in a P orbital. this provides slightly more shielding and a bigger atomic radius.

17
Q

ionisation energy between 5 and 6

A

There is a slight decrease due to there being 4 electrons in the p orbital so some repulsion occurs.

18
Q

The first ionisation energy definition.

A

The first ionisation energy of an element is the energy required to remove one electron from each atom in one mole of the gaseous element to form one mole of 1+ ions.

19
Q

What is metallic bonding?

A

Strong electrostatic attraction between cations (positive ions) and delocalised electrons.

20
Q

Properties of giant metallic lattices

A

High melting and Bp’s.

Good electrical conductors

Malleable and ductile as the delocalised electrons can move in the structure.

21
Q

What happens as you move across period 2 and 3?

A

The elements change from metal to non metal.

Solids to gases.

giant metallic, giant covalent and then to simple molecular.