2.2 Flashcards
What is Covalent bonding?
Electrostatic attraction between the positive nuclei of the atoms and the shared pair of electrons.
Dative covalent bond.
A bond that forms where both electrons are from the same atom.
what’s VSEPR theory?
The theory that negative electrons in a pair will repel eachother as far as possible.
What’s the name and angles for two elements joined to a middle one and three elements joined to a middle one.
2- linear (angle 180°)
3- trigonal planer (angle 120°)
Name and angles for 4, 5 and 6 elements joined to a central one.
4- tetrahedral (109.5°)
5- Trigonal bipyramidal (90° and 120°)
6- Octahedral (90°)
What’s a bent/ non-linear compound.
When there are lone pairs the electrons are drawn closer to the nucleus than the bonding pairs. the angles change by 2.5° each time.
What are Polar molecules?
When some electrons in a covalent bond have stronger attraction for electrons due to a greater electronegativity so one side is slight + or -
when do the dipoles cancel?
When the molecule is symmetrical
what are the different orbitals
s orbital- spherical (one orbital per level)
p orbital- dumbbell shape 90° to eachother (three orbitals per level)
d orbital- (five d orbitals per level)
what are the properties of ionic bonding?
soluble in water- the ionic compounds that carry higher charges on the ions tend to be less soluble as it’s more energy to break
hard and brittle- if they are shifted a small amount it would move one layer of ions causing repulsion
crystalline solids with high melting points
conducts electricity when molten
permeant dipole dipole bonds
molecules with permeant dipole will be attracted to other molecules with a permeant dipole as oppositely charged ions attract.
induced or temporary dipole dipole attraction
uneven electron position
creates a temporary dipole
which induces a neighbouring molecule
hydrogen bonding
bonding between molecules with N, O and F.
the hydrogen forms a bing with the lone pair of another molecule due to the dipoles
how does hydrogen bonds have an impact on water.
ice is less dense due to the open lattice like structure.
Water has a higher boiling point compared to similar molecules of the same size as hydrogen bonds take a lot of energy to break.
What is a sub shell?
An electron shell is made up of orbitals with the same principal quantum number.
With each shell orbitals are grouped together in a sub shell.
There are s,p,d and f orbitals.