2.2 Flashcards

1
Q

What is Covalent bonding?

A

Electrostatic attraction between the positive nuclei of the atoms and the shared pair of electrons.

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2
Q

Dative covalent bond.

A

A bond that forms where both electrons are from the same atom.

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3
Q

what’s VSEPR theory?

A

The theory that negative electrons in a pair will repel eachother as far as possible.

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4
Q

What’s the name and angles for two elements joined to a middle one and three elements joined to a middle one.

A

2- linear (angle 180°)

3- trigonal planer (angle 120°)

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5
Q

Name and angles for 4, 5 and 6 elements joined to a central one.

A

4- tetrahedral (109.5°)

5- Trigonal bipyramidal (90° and 120°)

6- Octahedral (90°)

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6
Q

What’s a bent/ non-linear compound.

A

When there are lone pairs the electrons are drawn closer to the nucleus than the bonding pairs. the angles change by 2.5° each time.

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7
Q

What are Polar molecules?

A

When some electrons in a covalent bond have stronger attraction for electrons due to a greater electronegativity so one side is slight + or -

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8
Q

when do the dipoles cancel?

A

When the molecule is symmetrical

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9
Q

what are the different orbitals

A

s orbital- spherical (one orbital per level)

p orbital- dumbbell shape 90° to eachother (three orbitals per level)

d orbital- (five d orbitals per level)

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10
Q

what are the properties of ionic bonding?

A

soluble in water- the ionic compounds that carry higher charges on the ions tend to be less soluble as it’s more energy to break

hard and brittle- if they are shifted a small amount it would move one layer of ions causing repulsion

crystalline solids with high melting points

conducts electricity when molten

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11
Q

permeant dipole dipole bonds

A

molecules with permeant dipole will be attracted to other molecules with a permeant dipole as oppositely charged ions attract.

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12
Q

induced or temporary dipole dipole attraction

A

uneven electron position

creates a temporary dipole

which induces a neighbouring molecule

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13
Q

hydrogen bonding

A

bonding between molecules with N, O and F.

the hydrogen forms a bing with the lone pair of another molecule due to the dipoles

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14
Q

how does hydrogen bonds have an impact on water.

A

ice is less dense due to the open lattice like structure.

Water has a higher boiling point compared to similar molecules of the same size as hydrogen bonds take a lot of energy to break.

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15
Q

What is a sub shell?

A

An electron shell is made up of orbitals with the same principal quantum number.
With each shell orbitals are grouped together in a sub shell.
There are s,p,d and f orbitals.

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16
Q

What is ionic bonding?

A

Electrostatic attraction between positive and negative ions.

17
Q

Properties of simple molecular structures.

A

Melting and Boiling points- low melting and bp because the intermolecular forces are weak so a small amount is needed to break them.

Electrical conductivity- non conductors.

Solubility- soluble in non polar solvents like hexane. weak temporary dipole forces are able to form between covalent molecules and these solvents.

18
Q

Giant covalent properties.

A

Melting and Boiling points- high melting and boiling.

Electrical conductivity- non conductors apart from graphite due to delocalised electrons between layers.

Solubility- insoluble in both polar and non polar solvents as the covalent bonds are too strong to break.