29: Naming and Physical Properties of Carbon Compounds Flashcards
What is the name of the functional group of alkanes?
There is no functional group since all bonds in alkane molecules are carbon-hydrogen single bonds or carbon-carbon single bonds.
What is the general formula of alkanes?
CnH2n+2
What is the name of the functional group of alkenes?
Carbon-carbon double bond
What is the general formula of alkenes?
CnH2n
What is the suffix of alkenes?
-ene
What is the name of the functional group of haloalkanes?
Carbon-halogen single bond (-X, where X is a halogen)
What is the general formula of haloalkanes?
RX, where X is a halogen.
What is the prefix of haloalkanes?
fluoro- / chloro- / bromo- / iodo-
What is the name of the functional group of alcohols?
Hydroxyl group
What is the general formula of alcohols?
ROH
What is the suffix of alcohols?
-ol
What is the name of the functional group of aldehydes?
Carbonyl group
What is the general formula of aldehydes?
(H or R)CHO
What is the suffix of aldehydes?
-al
What is the name of the functional group of ketones?
Carbonyl group
What is the general formula of ketones?
R1COR2
What is the suffix of ketones?
-one
What is the name of the functional group of carboxylic acids?
Carboxyl group
What is the general formula of carboxylic acids?
(H or R)COOH
What is the suffix of carboxylic acids?
-oic acid / -dioic acid
What is the name of the functional group of esters?
Ester group
What is the general formula of esters?
(H or R1)COOR2
What is the suffix of esters?
-yl -oate
What is the name of the functional group of unsubstituted amides?
Amide functional group
What is the formula of the functional group of unsubstituted amides?
CONH2
What is the general formula of unsubstituted amides?
(H or R)CONH2
What is the suffix of unsubstituted amides?
-amide
What is the name of the functional group of primary amines?
Amine functional group
What is the formula of the functional group of primary amines?
NH2
What is the general formula of primary amines?
RNH2
What is the suffix of primary amines?
-amine
What are the trends of boiling points within a homologous series?
As the carbon chain length increases, the boiling points increase as the number of electrons per molecule increases, which results in stronger van der Waals’ forces between the molecules. More energy is needed to overcome the van der Waals’ forces and separate the molecules.
What are the trends of water solubility within a homologous series?
If the functional group is able to interact with water, it will favour the solubility. However, the carbon skeleton is non-polar, and it does not help the solubility of the compound in water. Long carbon chains can counteract any solubility-favouring effect of the functional group, resulting in a decrease of solubility of carbon compounds of the same homologous series with increasing chain length.
What are the factors affecting the physical properties of a carbon compound?
The functional group it contains and the length of the carbon chain in the molecule.