2.5 Electrolysis Flashcards

1
Q

Electrolysis

A

Splitting up using electricity
OR
The chemical decomposition by passing electricity through a liquid or solution with ions in

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2
Q

What are electrodes usually made off?

A

An unreactive or inert substance e.g graphite or platinum

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3
Q

Can covalent compounds be electrolysed?

A

Cannot usually unless they react in water to form ions e.g acids in water

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4
Q

Why does the whole circuit keep working even though no electrons pass through the electrolyte in the beaker?

A

Because the ions transfer charge to continue the circuit. Eventually the circuit will stop when the solution/ electrolyte has run out/ electrolysed!

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5
Q

An electrode

A

An electrical conductor through which electricity enters or leaves a non-metallic object or substance e.g electrolyte

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6
Q

Anode

A

Positively charged electrode

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7
Q

Cathode

A

Negatively charged electrode

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8
Q

Electrolyte

A

A liquid or gel which contains ions and can be decomposed by electrolytes.

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9
Q

Electrolysis

A

Chemical decomposition produced by passing en electric current through a liquid or solution containing ions.

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10
Q

An ion

A

An atom or molecule with a charge due to the loss or gain of one or more electrons.

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11
Q

Compounds

A

Composed of 2 or more separate elements bonded together; a mixture

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12
Q

Diatomic atoms

A
Nitrogen
Hydrogen
Oxygen
Iodine
Bromine
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13
Q

How are chloride, bromide or iodide discharged at the positive electrode.

A

As chlorine, bromine or iodine.

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14
Q

What happens at the NEGATIVE ELECTRODE?

A

More reactive positive ions stay in solution, less reactive are discharged( lose charge go to electrode).

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15
Q

What happens at the POSITIVE ELECTRODE?

A

Order of discharge- halide> hydroxide ( when hydroxide ions are discharged, oxygen is given off)> all other negative charged ions.

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16
Q

Halogens

A

What elements in group 7 are known as and when charged called halides.

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17
Q

Oxidation

A

Loss of electrons (OIL RIG)

18
Q

Reduction

A

Is gain of electrons (OIL RIG)

19
Q

What are redox reactions?

A

Both reduction and oxidation take place.
E.g
PbBr2 👉 Pb + Br2

20
Q

What would a half equation for a positive electrode look like?

A

2Br- 👉 Br2 + 2e-

21
Q

What would a half equation for a negative electrode look like?

A

Pb2+ + 2e- 👉 Pb

22
Q

What is brine?

A

A solution of sodium chloride in water (NaCl dissolved in H2O)

23
Q

Test for hydrogen?

A

Squeaky ‘pop’ test, if place a burning splint into hydrogen gas, will make a ‘pop’ sound.

24
Q

Test for chlorine

A

Turns blue litmus paper red then bleached white.

25
Hydrogen in industry?
Primarily used as a reactant, but also a fuel in space. ``` Also used in; Fertiliser and paint industries Fuel cells Food and chemical industries Electrical generators Methanol production ```
26
Chlorine in industry?
``` Commonly used to make drinking water safe and to treat swimming pools, also used as an antiseptic. Also used in ; Production of paper products Plastics Dyes Textiles Medicines Solvents Paints ```
27
Sodium hydroxide industry?
``` A very common base used in the chemical industry, used drain and oven cleaners, oil refining, water treatment and metal processing. Also used in manufacture of; Fabric Plastic wrap Paper Soap ```
28
Some examples of electroplating?
Chromium- plated kettle Chromium- plated handlebars (bikes) Tin-plated steel can Gold/silver plated jewellery
29
Oxidation
Loss of electrons (OIL RIG)
30
Reduction
Is gain of electrons (OIL RIG)
31
What are redox reactions?
Both reduction and oxidation take place. E.g PbBr2 👉 Pb + Br2
32
What would a half equation for a positive electrode look like?
2Br- 👉 Br2 + 2e-
33
What would a half equation for a negative electrode look like?
Pb2+ + 2e- 👉 Pb
34
What is brine?
A solution of sodium chloride in water (NaCl dissolved in H2O)
35
Test for hydrogen?
Squeaky 'pop' test, if place a burning splint into hydrogen gas, will make a 'pop' sound.
36
Test for chlorine
Turns blue litmus paper red then bleached white.
37
Hydrogen in industry?
Primarily used as a reactant, but also a fuel in space. ``` Also used in; Fertiliser and paint industries Fuel cells Food and chemical industries Electrical generators Methanol production ```
38
Chlorine in industry?
``` Commonly used to make drinking water safe and to treat swimming pools, also used as an antiseptic. Also used in ; Production of paper products Plastics Dyes Textiles Medicines Solvents Paints ```
39
Sodium hydroxide industry?
``` A very common base used in the chemical industry, used drain and oven cleaners, oil refining, water treatment and metal processing. Also used in manufacture of; Fabric Plastic wrap Paper Soap ```
40
Some examples of electroplating?
Chromium- plated kettle Chromium- plated handlebars (bikes) Tin-plated steel can Gold/silver plated jewellery
41
Why do we electroplate?
Protect metal beneath from eroding. More attractive. Increase hardness and its resistance to scratching. Saves money by using a thin layer of a precious metal instead of the pure expensive metal. Helps people allergic to nickel- a metal often used to make cheap jewellery.
42
An electroplated object is..
Coated with a thin layer of metal by electrolysis.