2.15 SAPONIFIABLE AND NON SAPONIFIABLE LIPIDS Flashcards
● is a lipid that undergoes hydrolysis in basic solution to yield two or more smaller product molecules.
Saponifiable Lipids)
● five types of saponifiable lipid
(triacylglycerols, glycerophospholipids, sphingophospholipids, sphingoglycolipids, and waxes)
● a lipid that does not undergo hydrolysis in basic solution
nonsaponifiable lipid)
● four types of nonsaponifiable
cholesterol, bile acids, steroid hormones, and eicosanoids)
● What determines whether or not a lipid is saponifiable?
[ It is the types of linkages (bonds) that hold its component parts (building blocks)]
● Three types of linkages
[(1) ester linkages (2) amide linkages and (3) glycosidic linkages
● Triacylglycerol
three ester linkage)
● Glycerophospholipid
four ester linkages)
● Sphingophospholipid
one amide and two ester linkages)
● Sphingoglycolipid
one amide, one ester, and one glycosidic linkage
● Biological waxes
one ester linkage
● Structurally, these nonsaponifiable lipids have two things in common
(only one building block is present and
there is no need for ester, amide, or glycosidic linkages to be present to link building blocks together since there is only one building block.)
- In which of the following pairs of lipid types are both members of the pair classified as saponifiable lipids?
- triacylglycerols and biological waxes
- How many building blocks are present in the block diagram structure of a non saponifiable lipid
- one
- Which of the following statements concerning bond breaking that occurs under saponification conditions is incorrect?
- no correct response