1.6 The Periodic Table Flashcards

1
Q

periodic table trends

A
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2
Q

blocks

A
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3
Q
A
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4
Q

s-block elements, those found in Group 1 and 2, are metals that form

A

basic oxides

are reducing agents, so they donate electrons and form cations easily

melting point decreases down the group

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5
Q

p-block elements are non-metals that form

A

acidic oxides

are oxidising agents

Those in Group 6 and 7 can accept electrons and form anions easily.

Their melting point increases down the group.

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6
Q

d-block elements are

A

transition metals

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7
Q

oxidising agent

A

a species that accepts electrons, thereby helping oxidation. It becomes reduced itself in the process

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8
Q

which is the oxidising and reducing agent

A

the oxidising agent is Br2

the reducing agent is Na

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9
Q

The reducing agent is

A

a species that donates electrons, thereby helping reduction. It becomes oxidised itself in the process

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10
Q

oxidation and reduction

A

If a species increases in oxidation number, it is said to be oxidised. If it decreases in oxidation number, it is said to be reduced.

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11
Q
A

protons X

electrons

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12
Q
A

decreases x

increases

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13
Q
A

increases x

decreases

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14
Q
A

gains x

donates

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15
Q
A

donates x

gains

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16
Q
A
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17
Q
A
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18
Q
A
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19
Q
A
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20
Q

flame test colours

A
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21
Q

Practical method for flame tests

A

To carry out a flame test, dip a wire loop into concentrated hydrochloric acid and then hold in a roaring flame of a Bunsen burner to remove any contaminants.

Then dip the loop in the compound to be tested and hold again in the roaring flame. It is important that the flame has no colour so the colour of the compound can be seen. Observe any colour shown by the compound.

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22
Q

Oxides are formed when

A

the s-block metals come into contact with oxygen or air

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23
Q

group 1 oxidation

A
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24
Q

group 2 oxidation

A
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25
All the oxides formed are basic. This means they react with acid to give
a salt and water
26
Group 1 elements react with water
metals react more vigorously as you go down the group
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Group 2 elements react with water
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All precipitates are white. Write ionic equations for the formation of an insoluble salt
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โš›๏ธ Reactivity Trends in Group 1 and Group 2
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When heated, Group 2 carbonates undergo thermal decomposition
to produce an oxide and carbon dioxide gas.
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Group 2 Carbonates As you move down the group, this reaction happens more slowly as carbonates are more thermally stable the further down the group they are.
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Metal hydroxides
also decompose on heating, but they form an oxide and water
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Solubility of Group 2 Hydroxides
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Solubility of Group 2 Sulfates
The trend here is the opposite. Solubility decreases down the group. So, whilst magnesium sulfate is soluble, barium sulfate forms an insoluble white precipitate.
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๐Ÿงช Basic Character of Group 1 and Group 2 Oxides and Hydroxides
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โš–๏ธ Base Strength and Group Trends
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volatility group 7
the tendency to form a gas at room temperature, decreases down the group as does the melting point because the intermolecular forces holding the diatomic elements together get stronger as the atom gets bigger The increased number of electrons in the atom, as you go down the group, contribute to the increase of induced dipole โ€“ induced dipole interactions that hold the molecule together.
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reactivity group 7
The reactivity also decreases as you go down the group. This is because the oxidising power of the elements also decreases. This is due to the fact that larger atoms are less able to attract electrons.
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halogen + sodium
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halogen + iron
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silver halide precipitate ionic equation
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First add dilute nitric acid, HNO3(aq) followed by aqueous silver nitrate, AgNO3(aq) testing with aqueous ammonia, NH3, can be used to distinguish colour
50
The displacement reactions are another set of reactions that we can use to show how reactivity of the halogens decreases down the group. A more reactive halogen will displace a less reactive one from a solution of one its salts.
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chlorine add bromine ionic equation
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53
chlorine forms equillibrium with water
It needs to be added at concentrations below 1 part per million (ppm) in order to be beneficial. There is no real opposition to the addition of chlorine to water since it makes water safe to drink. Fluoride is added to toothpaste and water as it strengthens tooth enamel helping to prevent decay. It can also strengthen bones and prevent osteoporosis. Again, it needs to be added at concentrations below 1 part per million (ppm) in order to be beneficial. Higher doses in water can be harmful and discolour teeth. This is called fluorosis. Fluorine has also been linked to bone cancers and thyroid problems. Adding fluorine to water is therefore more controversial. Many people feel it is forced mass medication, taking away freedom of choice. Others argue that toothpaste provides sufficient doses of fluorine so adding it to the water is unnecessary.
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form copper(II) sulfate crystals soluble salt formation in which crystallisation is used to obtain the solid.
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Insoluble salts are made by
precipitation reactions in which an insoluble solid is formed when two solutions are mixed.
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Gravimetric analysis means
using the mass of the substance produced to quantify it. In this experiment an unknown chloride is going to be used and gravimetric analysis will allow us to calculate its molar mass and concentration in solution.
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Gravimetric analysis method
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gravimetric analysis calculations
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Qualitative analysis
is the process by which unknown salts are identified using chemical tests. Again, a video of this practical is available below.