1.45 pH Flashcards

1
Q

what is a hydronium ion?

A

a hydrated proton

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2
Q

what does the bronsted-lowry definition state about acids and bases?

A

acid - proton donor
base - proton acceptor

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3
Q

water is -, meaning…

A

amphoteric, it can react as an acid or a base

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4
Q

how is the dissociation of water (ionic product) represented?

A

Kw

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5
Q

what is the value of Kw at room temperature?

A

1 x 10-14

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6
Q

how does the value of the ionic product vary?

A

with temperature

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7
Q

what is formed when an acid donates a proton?

A

A conjugate base

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8
Q

what is formed when a base accepts a proton?

A

a conjugate acid

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8
Q

what is formed when a base accepts a proton?

A

a conjugate acid

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9
Q

how do strong acids/bases behave in solution?

A

completely dissociate into ions

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10
Q

how do weak acids and bases behave in solution?

A

only partially dissociate into ions

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11
Q

examples of strong acids?

A

hydrochloric, sulfuric, nitric

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12
Q

which bases are strong?

A

solutions of metal hydroxides

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13
Q

how do equimolar solutions of weak and strong acids/bases differ?

A

pH values, conductivity, reaction rates

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14
Q

what is the same about equimolar solutions of strong and weak acids/bases?

A

stoichiometry of reactions

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15
Q

how should the pH of a weak acid be calculated?

A

using pKa values

16
Q

soluble salt of strong acid strong base produces…

A

a neutral solution

17
Q

salt of weak acid strong base produces…

A

alkaline solution

18
Q

salt of strong acid weak base produces…

A

acidic solution

19
Q

how does strong acid/weak base affect the water equilibrium?

A

the weak base ion removes OH-, causing water equilibrium to shift right producing excess hydronium

20
Q

how does weak acid/strong base affect the water equilibrium?

A

the weak acid ion removes H30+, causing water equilibrium to shift right producing excess OH-

21
Q

how does strong acid/strong base affect the water equilibrium

A

neither ion has an impact so hydronium and Oh- concentrations remain equal

22
Q

what is a buffer solution?

A

one in which the pH remains approximately constant when small amounts of acid, base or water are added

23
Q

what does an acid buffer consist of?

A

a solution of a weak acid and one of its salts made from a strong base

24
how does an acid buffer work?
- the weak acid provides hydrogen ions (when a small amount of base removes them) - the salt of the weak acid provides the conjugate base which absorbs excess hydrogen ions (when a small amount of acid adds them)
25
what does a basic buffer consist of?
a solution of a weak base and one of its salts
26
how does a basic buffer work?
the weak base removes excess hydrogen ions the conjugate acid provided by the salt supplies hydrogen ions when these are removed
27
how is the acid indicator dissociation constant represented?
as Kin
28
in solution the colour of a acid indicator is ... from that of its conjugate base
distinctly different
29
what is the equivalence point?
the midpoint of rapid increase in pH
30
which indicator would be suitable for strong acid/strong base?
one which changes colour around pH 7
31
which indicator would be suitable for strong acid/weak base?
one which changes colour at an acidic pH
32
which indicator would be suitable for weak acid/strong base?
one which changes colour at basic pH
33
why is it not possible to select a suitable indicator for weak acid/weak base?
the pH does not change rapidly enough at the end point
34
indicators are...
weak acids
35
what is the colour of the indicator determined by?
the ratio of HIn to In-
36
what is the theoretical point at which colour change occurs?
when H30+ = KIn
37
when is the colour change of an indicator assumed to be distinguishable?
when HIn and In- differ by a factor of 10
38
the pH range over which a colour change occurs can be estimated be the expression
pH = pKIn ± 1