1.26 shapes of molecules Flashcards
which shape is formed from 6 electron pairs, 2 non-bonding?
square planar
what are the bond angles in a T-shaped molecule?
less than 90 and 120
which shape does 5 electron pairs, 2 non-bonding, form?
T -shaped
what is the bond angle in an angular shape?
105 degrees
which shapes does 4 electron pairs, 2 non-bonding, form?
angular
what is the bond angle in a trigonal pyramidal shape?
107 degrees
which shape does 4 electron pairs, one non-bonding, form?
trigonal pyramidal
how can you determine if there are any non-bonding pairs?
by subtracting the number of atoms around the central atom from the number of pairs
in which order do repulsive effects decrease?
non-bonding : non-bonding > non-bonding : bonding > bonding : bonding
why do non-bonding pairs from distorted shapes?
they have a greater repulsive effect than bonding pairs
what is a dative bond?
when both electrons come from the same atom
what is the bond angle in an octahedral shape?
90 degrees
what are the bond angles in a trigonal bipyramidal shape?
90 (between planar and upper part) and 120 (between planar part)
what is the bond angle in a tetrahedral shape?
109.5 degrees
what is the bond angle in a trigonal planar shape?
120 degrees
what is the bonding angle in a linear shape?
180 degrees
which shape does 6 bonding electron pairs form?
octahedral
which shape does 5 bonding electron pairs form?
trigonal bipyramidal
which shape does 4 bonding electron pairs form?
tetrahedral
which shape does 3 bonding electron pairs form?
trigonal planar
which shape does 2 bonding electron pairs form?
linear
what are the steps used to calculate the number of electron pairs around the central atom?
- count the number of outer electrons on the central atom
- add 1 for each atom attached to the central atom
- add electrons if the ion is negative, subtract if it sis positive
- divide the total number by 2
what determines the shape of a molecule?
the number of electron pairs around the atom
why do molecules adopt a particular shape?
to minimise the repulsive forces of the shared electrons in a covalent bond