1.3 Enhancement of materials Flashcards
What is material enhancement?
a way of improving a material’s properties to better suit the requirement of the final product?
What are the 5 ways a polymer can be enhanced through the use of additives?
1 make polymers easier and less expensive to process
2 enhance aesthetics
3 improve product function
4 prolong life (prevent degradation)
5 encourage degradation
What are the 2 additives that help to make the polymer flow more easily into the mould?
- Lubricants
- Thermal antioxidants
What is the additive used to enhance aesthetics?
pigments
What are the 4 additives used to improve produce function?
- antistatics
- flame retardants
- plasticisers
- fillers
What are the 2 additives used to prolong life (prevent degradation)?
- antioxidants
- UV light stabilisers
What are the 2 additives used to encourage degradation?
- biodegradable plasticisers
- bio-batch additives
What do lubricants do?
The addition of wax or calcium stearate reduces the viscosity of the molten polymer, making it less sticky, allowing more intricate shapes to be formed.
They can also allow the moulding temperature to be lowered, saving energy during the manufacturing process.
What do thermal antioxidants do?
these help to prevent the polymer oxidising or discolouring due to excessive heat during processing.
What do pigments do?
these are tiny particles that are mixed into the polymer in its molten state to give colour to the final processed product.
what do antistatics do?
Due to their poor electrical conductivity, plastics are used for insulating products. This insulating property can lead up to a build-up of static electrical charge, which attracts dirt and dust. The addition of antistatics improves the surface conductivity by attracting moisture from the room surroundings, therefore reducing static charge.
What do flame retardants do?
Bromine, chlorine, phosphorus or metal, when added to polymers reduce the likelihood of combustion or the spread of fire. This is particularly important in products exposed to heat, such as car engine components or potential electrical fires such as plug sockets.
What do plasticisers do?
These are added to allow plastics to become less hard and brittle at room temperature use.
They are added to LDPE in the manufacture of food wrap, allowing the wrap to be stretched over the food product.
They also help in processing because they allow polymers to be easily formed at higher temperatures.
What do fillers do?
To provide bulk for the product (meaning less polymer is required) and to improve the polymer properties.
Commonly used fillers are sawdust and wood flour as well as mineral fillers such as chalk, clay and calcium carbonate. Sawdust and flour provide bulk, therefore reducing the amount of polymer required for the product. Mineral fillers can help to increase the thermal conductivity of the polymer, meaning they will heat up and cool down more quickly, giving shorter mould cycle times.
What do antioxidants do?
They help to reduce the environmental deterioration of the polymer from exposure to oxygen in the air.
Polymer degradation can lead to increased brittleness, surface cracks and pigment discolouration.
What do UV light stabilisers do?
They prevent the polymer chains from being broken down by sunlight. UV attack causes the polymer to lose colour and become more brittle.
What do biodegradable plasticisers do?
Similar to plasticisers used to enhance processing, these make the polymer more flexible, softer and easier to break down, which means a faster degradation time.
What do bio-batch additives do?
Oxy-degradable (degrade in the presence of oxygen), photodegradable (degrade when exposed to UV light) and hydro-degradable (degrade in the presence of water) additives can be added to polymers to help recue the degradation time from hundreds of years to a few years or even months.