11. Introduction to organic chemistry Flashcards

1
Q

Name all the ways organic compounds can be represented

A

-empirical formula
-molecular formula
-general formula
structural formula
-displayed formula
-skeletal formula

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2
Q

Define empirical formula

A

Formula that shows the simplest ratio of the atoms of each element present in a compound

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3
Q

Define molecular formula

A

Formula that shows the actual number of atoms of each element in the molecule

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4
Q

What is a displayed formula

A

Shows every atom and every bond in a molecule

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5
Q

What is a structural formula

A

Shows the unique arrangement of atoms in a molecule in a simplified form, without showing all the bonds

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6
Q

What is skeletal formula

A

Shows carbon-carbon bonds. Neither C or H bonds are drawn

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7
Q

Define functional group

A

An atom or group of atoms in an organic molecule which is responsible for the characteristic reactions of that molecule

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8
Q

What is a homologous series

A

A family of organic compounds with the same functional group but different chain lengths

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9
Q

Define isomer

A

Molecules that have the same molecular formula but whose atoms are arranged differently

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10
Q

Name the two types of isomerism

A
  • structural

- stereoisomerism (geometric)

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11
Q

Name the three sub divisions of structural isomerism

A
  • positional
  • functional
  • chain
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12
Q

What is positional isomerism

A

Where the same functional groups are attached to the main chain at different points

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13
Q

What is functional isomerism

A

Where functional groups are different

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14
Q

What is chain isomerism

A

Where there is a different arrangement of the hydrocarbon chain

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15
Q

What is structural isomerism

A

They have the same molecular formula but different structural formula

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16
Q

What is stereoisomerism

A

Where molecules have the same structural formula but differ in the arrangement of the bonds in space

17
Q

Name the two types of stereoisomerism

A
  • ez

- optical

18
Q

What is ez isomerism

A

Tells us about the positions of the substituents at either side of a carbon double

19
Q

Why do ez isomers exist

A

Substituted groups around a single bond can rotate so there are no isomers
There is no rotation around a double bond so E and Z isomers are separate compounds

20
Q

What is the different between E and Z isomers

A
  • Z isomers (zusammen, together) two substitutions are on the same side of the bond
  • E isomers (entgegen, opposite) two substitutions are on the opposite side of the bond