▪️🔹1.1 Carbohydrates -chemical elements Flashcards

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1
Q

What type of compounds are carbohydrates?

A

Organic compounds

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2
Q

What elements do carbohydrates contain?

A

Carbon, hydrogen and oxygen

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3
Q

What is the basic unit of a carbohydrate?

A

A monosaccharide

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4
Q

What do two monosaccharides combine to form?

A

A disaccharide

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5
Q

What do many monosaccharide molecules combine to form?

A

A polysaccharide

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6
Q

What are monosaccharides?

A

Small organic molecules that are the building blocks for larger carbohydrates

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7
Q

What is the general formula of monosaccharides?

A

Cn(H2O)n

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8
Q

Name the value (n) of carbon atoms in triose and hexose

A
Triose= 3 carbon atoms 
Hexose= 6
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9
Q

Give an example of a hexose carbohydrate?

A

Glucose is a hexose sugar

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10
Q

How many isomers does glucose have an what are these?

How do these differ?

A

2 isomers
a- glucose and B- glucose
They are based on the different positions of an (OH) and (H) in the structure of the molecule

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11
Q

What does the different forms of glucose result in?

A

The biological differences of polymers such as starch and glucose

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12
Q

Define monosaccharide

A

An individual sugar molecule

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13
Q

Name 4 functions of monosaccharides

A

1) source of energy in respiration
2) building blocks for larger molecules e.g glucose makes polysaccharides starch, glycogen and cellulose
3) parts of nucleotides (D in DNA, R in RNA)
4) intermediates in reactions (triose are intermediates in reactions of respiration and photosynthesis)

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14
Q

How are disaccharides formed?

A

Composed of 2 monosaccharides bonded together with the formation of a glycosidic bond and the elimination of water (condensation reaction)

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15
Q

Name the monomers present in, and biological role of maltose

A

Glucose + Glucose

Needed for germinating seeds

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16
Q

Name the monomers present in, and biological role of sucrose

A

Glucose + fructose

Needed for transport in the phloem of flowering plants

17
Q

Name the monomers present in, and biological role of lactose

A

Glucose + galactose

Found in mammalian milk

18
Q

Which test tests for reducing sugars?

Name the positive result

A

Benedicts test

Blue - green -orange —> brick red

19
Q

Why do non-reducing sugars not change during a normal Benedicts test?

A

Because the disaccharide is not broken down to its monosaccharides, this is done by heating with hydrochloric acid and then adding alkali, positive result should now occur

20
Q

Name an enzyme that can detect sucrose by hydrolysing it into glucose and fructose
Name a negative of this

A

Sucrase

It is specific, only hydrolyses sucrose no other non reducing sugars

21
Q

How can you get a quantitative measurement of the concentration of sugar

A

Using a biosensor, provides an accurate measurement, used in conditions such as diabetes

22
Q

Define a polymer

A

A large complex polymer formed from large values of monosaccharides linked by glycosidic bonds

23
Q

Why is starch (a polysaccharide) a better storage product in the body than glucose (reasons why we convert starch to glucose)

A

1) starch is insoluble so has no osmotic effect
2) you can’t diffuse out of a starch cell
3) starch is a compact molecule and can be stored in a small space
4) starch carries a lot of energy in its C-H and C-C bonds

24
Q

What is starch made out of?

A

A-glucose molecules bonded in two different ways forming amylose and amylopectin

25
Q

Describe amylose

A

1)linear unbranched molecule with a-1-4 glycosidic bonds between (C1) and (C4) in the next.
2)repeated, forming a chain which could into a helix
(Need to know how it’s drawn)

26
Q

Describe amylopectin

A

-chains of glucose monomers joined with a-1-4 glycosidic bonds
-these are cross linked within a-1,6-glycosidic bonds.
(Need to know how it’s drawn)

27
Q

Describe a test to identify starch

A

The iodine, potassium iodide test
Colour change = orange/brown —> blue/black
Qualitative test not quantitive

28
Q

What is glycogen used for?

A

The main storage product in animals

29
Q

Describe the structure of glycogen

A

Similar to amylopectin it has a-1,4 and a-1,6 bonds but glycogen molecules have shorter a-1,4 linked chains so are more branched than amylopectin
(Learn diagram)

30
Q

What is the purpose of cellulose

A

Structural polysaccharide found in plant cell walls

31
Q
  • Describe the structure of the polysaccharide cellulose?

- What rotates the glucose molecules by 180 degrees

A

Has many long parallel chains of B-glucose
Glucose monomers are joined by B-1,4 glycosidic bonds
-the B- link rotates the adjacent molecules by 180 degrees which allow hydrogen bonds to form between the OH groups of adjacent parallel chains creating stability

32
Q

Describe the different layers inside cellulose

A

1) 60-70 cellulose molecules are tightly corsslinked to form microfibrils
2) micofibrils are held in bundles called fibres
3) cell wall has many givers that run parallel within a layer but at an angle to adjacent layers
4) laminated structure contributes to cell walls strength

33
Q

Explain how cellulose fibres are permeable

A

Because of the spaces between the fibres, this allows water and it’s solutes to penetrate through the spaces in the cell wall to access the cell membrane

34
Q

Where is chitin (structural polysaccharide) found?

A

In the exoskeleton if insects and in fungal cell walls

35
Q

Describe the structure of chitin

A

Has long chains of B-1,4 linked monomers with groups derived from amino acids added to form a hetropolysaccharide
-monomers are rotated through 180 degrees and chains are cross linked by hydrogen bonds, forming microfibrils