x Flashcards
Alkenes can be prepared by
elimination of alcohols forms alkenes reagent: concentrated Al2O3
Base induced elimination of HALOALKANESs (monohaloalkanes undergo elimination reaction to form alkene). Reagent: alcoholic KOH/NaOH
Alkanes oxidised to form alkenes reagent: Al2O3
Haloalkanes can be prepared by
Alkanes can undergo substitution/addition to form haloalkanes (Br or Cl)
Alkenes can undergo substitution to form dihaloalkanes (Br or Cl)
Alkenes can undergo substitution to form haloalkanes using reagent: HCl.
Other reactions of haloalkanes
Haloalkanes react with alcoholic alkoxides to form ethers
Haloalkanes react with aqueous alkali (NaOH/KOH) to form alcohol (under reflux)
Haloalkanes react with alcoholic cyanide to form nitriles (KCN)
Alcohols can be prepared by
Alkenes undergo an acid-catalysed hydration reaction with water using an acid catalyst to form alcohols reagent: water
Haloalkanes by nucleophilic substitution reagent: alkali OH (KOH)
Ketones reduce to form secondary alcohols reagent: LiAlH4
Aldehydes reduce to form primary alcohols reagent: LiAlH4
hydrolysis of an ester c=0,0
Carboxylic acids can be prepared by
Oxidising primary alcohols using reagent: acidified permanganate
Oxidising aldehydes using reagent: dilute h2so4
Nitriles hydrolysis form carboxylic acids using “H+
and H2O”
Amides hydrolyse using naoh/koh
ester hydrolysis using koh
Anything forming ester c=o o, is condensation using sulfuric acid
.
Ethers can be prepared by
Nucleophilic substitution by reacting a monohaloalkane with reagent: alkoxide (ch3o)
nitriles
Can be prepared from a haloalkane reagent: alcoholic CN by reflux
amines
Can be prepared from nitriles using reagent liAlh4
Ketones
Oxidised from alcohol using mno4-
Aldehydes
Oxidised from alcohol using mno4-
Benzene can be prepared using catalyst aluminium chloride
.
Reagent to produce ethoxide is Sodium metal
.
Benzene
Nitration and sulfonation of benzene uses concentrated sulfuric acid
esters can be produced by
condensation of an alcohol, or carboxylic acid using h2so4
amides can be produced by
condensation of carboxylic acid and amines