x Flashcards

1
Q

Alkenes can be prepared by

A

elimination of alcohols forms alkenes reagent: concentrated Al2O3

Base induced elimination of HALOALKANESs (monohaloalkanes undergo elimination reaction to form alkene). Reagent: alcoholic KOH/NaOH

Alkanes oxidised to form alkenes reagent: Al2O3

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2
Q

Haloalkanes can be prepared by

A

Alkanes can undergo substitution/addition to form haloalkanes (Br or Cl)

Alkenes can undergo substitution to form dihaloalkanes (Br or Cl)

Alkenes can undergo substitution to form haloalkanes using reagent: HCl.

Other reactions of haloalkanes
Haloalkanes react with alcoholic alkoxides to form ethers

Haloalkanes react with aqueous alkali (NaOH/KOH) to form alcohol (under reflux)

Haloalkanes react with alcoholic cyanide to form nitriles (KCN)

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3
Q

Alcohols can be prepared by

A

Alkenes undergo an acid-catalysed hydration reaction with water using an acid catalyst to form alcohols reagent: water

Haloalkanes by nucleophilic substitution reagent: alkali OH (KOH)

Ketones reduce to form secondary alcohols reagent: LiAlH4

Aldehydes reduce to form primary alcohols reagent: LiAlH4

hydrolysis of an ester c=0,0

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4
Q

Carboxylic acids can be prepared by

A

Oxidising primary alcohols using reagent: acidified permanganate

Oxidising aldehydes using reagent: dilute h2so4

Nitriles hydrolysis form carboxylic acids using “H+
and H2O”

Amides hydrolyse using naoh/koh

ester hydrolysis using koh

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5
Q

Anything forming ester c=o o, is condensation using sulfuric acid

A

.

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6
Q

Ethers can be prepared by

A

Nucleophilic substitution by reacting a monohaloalkane with reagent: alkoxide (ch3o)

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7
Q

nitriles

A

Can be prepared from a haloalkane reagent: alcoholic CN by reflux

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8
Q

amines

A

Can be prepared from nitriles using reagent liAlh4

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9
Q

Ketones

A

Oxidised from alcohol using mno4-

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10
Q

Aldehydes

A

Oxidised from alcohol using mno4-

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11
Q

Benzene can be prepared using catalyst aluminium chloride

A

.

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12
Q

Reagent to produce ethoxide is Sodium metal

A

.

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13
Q

Benzene

A

Nitration and sulfonation of benzene uses concentrated sulfuric acid

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14
Q

esters can be produced by

A

condensation of an alcohol, or carboxylic acid using h2so4

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15
Q

amides can be produced by

A

condensation of carboxylic acid and amines

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16
Q

amides can hydrolyse to produce

A

carboxylic acids and amines using koh