What factors affect the yield of chemical reactions? Flashcards
What are reversible reactions?
most chemical reactions are like: reactants -> products
the reaction is complete - it is an irreversible reaction - it cannot be reversed
although, some reactions are reversible.
a reversible reaction can go forwards or backwards if the reaction conditions are changed
What is dynamic equilibrium?
a reversible reaction can reach equilibrium ( a balance) which means the rate of the forward reaction is equal to the rate of the reverse reaction
What is a closed system?
where the conditions of the reaction (such as temperature of pressure) are not changed and no substances are added or removed
What is in a closed system at equilibrium?
there is no change in the amounts and concentrations of reactants and products
reactants are reacting to form products and products are reacting to re-form reactants at the same rate
this is called dynamic equilibrium
How can you change the equilibrium?
by changing the temperature, pressure, concentration of the reactants or products
if the equilibrium is the right of the reaction, the concentration is greater of the products than the concentration of the reactants
if the equilibrium is to the left of the reaction, the concentration of the products is less than the concentration of the reactants
What is Le Chatelier’s Principle?
when the conditions of a system are changed, the position of the equilibrium changes to try and restore the original conditions
we can then make predications about - what will happen when certain conditions are changed and what conditions need to be changed to make the highest yield of a substance
What is exothermic?
if a reaction is exothermic in the reactant - product direction, le chatelier’s principle shows that increasing the temperature will -
decrease the yield of the products
increase the amount of reactants
What is endothermic?
if a reactant is endothermic - then an increase in temperature will -
increase the yield of products
decrease the amount of reactants
What do pressure changes only apply to?
reactions involving gases
What do pressure changes change?
the equilibrium if there is a difference in the amount of gas in the products and reactants
What does an increase and decrease in pressure lead to?
increase in pressure = more product
decrease in pressure = equilibrium will move towards the side of the equation with the greatest number of moles