Week 6 - Theories of Covalent Bonding I Flashcards
A covalent bond forms when…
orbitals of two atoms overlap and a pair of electrons occupy the overlap region
single bond =
1 sigma bond
double bond =
1 sigma bond + 2 pi bonds
Can valence bond theory predict bond angles?
Not for all molecules
What can Valence Bond Theory vs VSEPR theory predict?
VBT - can predict orbitals involved but cannot predict the geometry for all molecules
VSEPR - can predict geometry for molecules but not the orbitals involved in bonding
if you mix two valence orbitals, you get…
two equivalent (atomic hybrid) orbitals - and so on
number of electron groups =
= number of hybrid orbitals
Triple bond =
2 sigma bonds + 2 pi bonds
say you’re mixing 1 s orbital, 3 p orbitals, and 2 d orbitals; what is the hybrid bond called?
s p^3 d^2 σ bond