Week 4 - Models of Chemical Bonding Flashcards

1
Q

Lewis Symbols

A

An element symbol with valence electrons denoted by dots around it, generally only written for main group elements.

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2
Q

Octet rule

A

atoms tend to fill their valence orbital with eight electrons

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3
Q

Three ways atoms achieve noble gas configuration, and which groups do each way?

A
  1. Lose electrons, form cations (groups 1, 2, 13)
  2. Share electrons, form covalent bonds (groups 13-17)
  3. Gain electrons, form anions (groups 16-17)
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4
Q

When metals and nonmetals bond…

A

electrostatic interactions between cation and anion form ionic bonds

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5
Q

When nonmetals and nonmetals bond…

A

shared electrons form covalent bonds

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6
Q

When metals and metals bond…

A

electron pools of delocalized electrons form metallic bonds

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7
Q

Ionic bonding is formed between…

A

metals and nonmetals

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8
Q

What is enthalpy and the symbol for it?

A

Change in enthalpy is the heat absorbed or released under constant pressure. It is symbolized by ∆H.

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9
Q

+ vs - enthalpy

A

+: endothermic (gets colder)
-: exothermic (gets hotter)

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10
Q

What is lattice energy?

A

The enthalpy change associated with lattice destruction

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11
Q

Which area in the periodic table do elements tend to have highest lattice energy?

A

Top right

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12
Q

Covalent bonds

A

Formed from sharing of electrons, each bond is 2 shared electrons, nonmetals with nonmetals

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13
Q

What do atoms achieve when forming covalent bonds?

A

Noble gas configuration

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14
Q

Between a single, double, and triple CC bond, what is the bond order, length, and energy between the three?

A

In order of single, double, triple:

order - 1, 2, 3
length - longest, middle, shortest
energy - least, middle, most

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15
Q

Bond energy increases as the elements are where on the periodic table?

A

Higher

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16
Q

Bond Energy

A

the energy required to overcome the attraction between nuclei and shared electrons. AKA bond enthalpy or strength.

17
Q

Is bond breakage exo or endothermic?

A

Endothermic

18
Q

Is bond formation exo or endothermic?

A

Exothermic

19
Q

How is enthalpy of a reaction calculated, and what is the symbol?

A

Bonds broken - formed, ∆rHᵒ

20
Q

When a covalent bond is formed between two different elements, the electron sharing is…

A

not equal

21
Q

What is electronegativity and its symbol?

A

The ability of an element to attract bonding electrons, ꭓ

22
Q

What causes a bond to be polar?

A

∆ꭓ of 0.5 or higher; high difference in electronegativity between the atoms leads to unequal sharing of electron pair.

23
Q

Atomic radius and electronegativity have a ________ relationship

A

inverse

24
Q

Molecular Formula vs Lewis Structure vs Condensed Formula: C4H10

A

MF: C4H10
LS: drawn out
CF: CH3CH2CH2CH3

25
Q

Exceptions to the octet rule

A
  • elements of row 3 and below can hold more than 8 electrons
  • electron deficient molecules can hold less than 8 electrons
  • odd-electron species contain an unpaired electron (free radicals) so can hold less than 8 electrons
26
Q

Bond energy and length have a ______ relationship.

A

Inverse