Week 4- Ocean acidification and atmospheric circulation Flashcards
Pteropods
Free-swimming sea snails
Potato chip of the sea
Imp source of food
Ocean acidification
Significant and harmful consequence of excess carbon dioxide in the atmosphere and therefore excess amounts being absorbed by the ocean
(increased CO2 and decreased pH)
How long does it take for the entire ocean system to become buffered?
1000 - 100,000 years
Acidity
Conc of H+ in solution
What happens ito pH f concentration of H+ increases
Decreases becoming more acidic
What has happened to CO2 and pH since Industrial revolution?
30% of CO2 released into atmosphere has been absorbed by ocean
Ocean pH has decreased by 0.11 (30% increase in H+ conc)
What does buffering do?
Prevents seawater from experiencing large changes in pH
What is the equation for when seawater is too basic?
H2CO3———-HCO3- + H+
*pH drops
What is the equation for when seawater is too acidic?
HCO3- + H+ ———- H2CO3
*pH rises
When CO2 enters the ocean, what types of carbon does it create?
- Bicarbonate ion (HCO3-)
- Carbonate ion (CO3^2-)
- Carbonic acid (H2CO3)
OVERALL BUFFERING EQUATION
CO2 + H2O<==>H2CO3 <==> H+ + HCO3- <++> 2H+ + CO3^2-
Calcite
- Varying amounts of MG2+ trigonal crystal system
- Stable state
- Plankton, sponges, brachiopods, echinoderms, bivalves (shell)
- High Mg and/or low Mg calcite
Aragonite
- Orthorhombic crystal system
- Metastable state
- Greater solubility
- Corals, pteropods, molluscs
- All Mg
What does buffering produce and what does it do?
Bicarbonate which moves pH towards neutral
Why is the ocean not buffering?
Buffering can’t keep up with the speed at which CO2 is changing the oceans pH