Week 4 - energy and metabolism Flashcards
Kinetic energy
Energy of motion/ movement associated w/ movement of organisms cells or organelles
potential energy
energy, stored, available to do work due to structure or location.
chemical energy
type of potential energy → available for release in a chemical reaction
chemical bonds
- molecules like glucose and triglyceride → store energy in their bonds
- to release the energy, the cell breaks the bonds
- if the cell cannot capture the energy being released, it wil be lost as heat
heat/ thermal energy
type of kinetic enrgy - associated w/ random movement of atoms or molecules
First law of thermodynamics
- law of conservation of energy,
- energy cannot be created or destroyed
- can be transformed from one type to another
Second law - thermodynamics
transfer or transformation of energy from one form to another. inc entropy or degree of disorder of a system
chemical reactions - endogenic
- requires an input of energy
- the chief currency of all cells use their energy transactions in adenosine triphosphate (ATP_
- cells store and release energy in bonds of ATP
Endergonic
reactions that form bonds to build molecules require energy input
Exergonic
- reactions that break bonds to release energy stored in bonds
chemical reactions - spontaneous
SPONTANEOUS CHEMICAL REACTIONS REQUIRE ACTIVATION ENERGY TO BE OVER COME OR REDUCED
activation energy
- INITIAL INPUT OF ENERGY TO START REACTION
- allows molecules to get close enough to case bod rearrangement → can not achieve state where bonds are stretch
2 ways to overcome: LARGE AMOUNTS OF HEAT or using ENZYMES to lower activation energy
enzyme
protein that acts as a catalyst → speeds up a chemical
substrate
- molecules that bind to the enzymes active siite , where chemical reaction occurs.
enzyme-substrate eg.
- substrate, sucrose, consists of glucose & fructose bond together
- substrate binds to the active site of the enzyme, forming an enzyme substrate complex
- the binding of the substrate & enzyme places stress on the glucose- fructose bond & bond breaks
- products are released & enzyme is free to bind w/ other substrates
energy - cellular level
- subtances are modified, small molecules are combined to generate larger macromolecules & vise versa
- CELLULAR RESPIRATION extracts energy stored in fuel molecule → cells use this to perform various works
chemical reactions - metabolism
- building complex molecules out of simple parts (monomers) forms new chemical bonds
- break complex molecules into simple parts break apart like chemical bonds → energy out
ATP cycles
- ATP is a renewable resource that is regenerated by addition of a phosphategroup to adenosine diphosphate ADP
- the energy to phosphorylate ADP comes form catabolic reactions in the cell.
- the chemical potential energy ‘ temporarily’ stored in ATP drives cellular work
ATP and coupling
- cells manage energy resources by ENERGY COUPING the use of an exergonic process to drive an endergonic one
- most energy couping in cells is mediated by ATP
competitivity
competitive: blocks access point to active site
non-competetive: changes shape of active site
enzymes - optimum temperature
CHANGES RATE OF MOLECULAR MOTION
- inc temp inc. molecular motion → inc. rate of catalyst
- OPTIMUM TEMP: temp at which the enzyme has the highest rate of catalysis
- dec temp. decreases molecular movement →decreases rate of catalysis
enzymes - temperature
CAUSES CHANGE IN SHAPE OF ENZYME
- changes above optimum temp will affect enzyme structure
- can no longer bind to sunstrate and catalyse a reaction
- if temp increases and is too high, will cause enzyme to denature
enzymes - pH
in basic enviro: acidic side chains could donate protons
in acidic enviro: basic side chains could accept protons
both events will change shape of enzyme → making it less able to bind w/ substrate, less able to catalyse reaction
free energy (delta G + metabolism
- Free energy: energy that can be used to do work when chemical bonds are bropken
- chemical reactions break some bonds in the reactant and form new ones in products
- in some reactions the products contain less free energy than reactants & release excess energy