Week 1 - chemicals building life Flashcards
water
- COHESION: of water via hydrogen bonds create SURFACE TENSION
- electronegativity creates a polar molecule w/ hydrogen bonding
isomers
structural: diff C skeleton
stereoisomers: same C skeleton
- differ in how groups attached
- enantiomers: D- sugars & L- AA
carbon
- can form up to 4 covalent bonds
- hydrocarbons: molecules of carbon & hydrogen
- nonpolar
- function groups: hydroxyl, carbonyl, carbooxyl, amino, sulfhydryl, phosphate, methyl
lipids
- insoluble → hydrophobic
- terpenes
- steroids
- prostaglandins
- in water, phospholipids form a BILAYER
lipids- triglycerides
- 1 glycerol + 3 fatty acids
- saturated: no double bond between C atoms → high melting point in ANIMALS
- unsaturated: 1 or more double bonds →low melting point in PLANTS
lipids - steroids
carbon skeleton is bent to form four fused rings
CHOLESTEROL: base steroid produces other steroids
proteins - functions
- enzyme catalysis
- defence
- transport
- support
- motion
- regulation
- storage
proteins - amino acid structure
- central carbon atom
- amino grtoup (NH2)
- carboxyl group (COOH)
- single hydrogen
- variable R group
proteins - peptides
- amino acids joined by dehydration - peptide bond
- long chains of AA spontaneously fold up
- FOLDING: congregation of hydrophobic AA in interior of protein & hydrophilic AA on ext
AA composition:
- hydrophobicity = solubility
- cysteine cont = stability
STRUCTURE DEFINES FUNCTION
proteins - levels of structure
- seq. of amino acids
- interaction of groups in peptide backbone: alpha helix & beta sheet
- folded, stabilised by forces →final level of structure: single PP chain
- arrangement of subunits → 2+ polypeptide
RNA
- ribose not deoxyribose
- uracil not thymine
- single polynucleotide strand
- specifies seq. of amino acids proteins
nucleic acid - nucleotide
Monomer: nucleotide → sugar + phosphate+ nitrogenous base
- PURINES: adenine, guanine
- PYRIMIDINES: thymine, cytosine, uracil
- nucleotides connected by PHOSPHODIESTER BONDS
DNA
encodes info
- AA seq. in protein
- base seq in DNA
double helix
- 2 polynucleotide strands
- hydrogenbonds
carbohydrates - function
- provide structure
- short & long term storage of energy
- part of nucleic acid backbone
- combine w/ proteins (glycoprotein)
- combine w/ lipids (glycolipids)
- involved in intracellular interactions between animal cells
carbohydrates - structure
MONOSACCHARIDE - simplest
DISACCHARIDE: transport or storage
POLYSACCHARIDE (dehydration) : storage: starch ; glycogen || struc supp: cellulose, chitin
- D-Glucose: most common → product of photosynthesis
- glycogen: in humans + broken down to release glucose when needed