Water and Wastewater Flashcards
Acidity
ability of a solution to neutralize hydroxide, arises from CO2 release during biological activity
Alkalnity
ability of a solution to neutralize hydrogen ions
MCL
maximum contaminant level: enforceable standards set by EPA
Primary drinking water standards
derived from MCLs, continuously revised
Secondary contaminant standards
nonenforceable, based on aesthetics
pH
describes the alkalinity/acidity of a solution- the higher the hydrogen ion concentration, the higher the acidity
Bicarbonate (HCO3-) is the primary source of…
… alkalinity in natural waters
To express the alkalinity of a solution….
… all species are converted to equivalents of CaCO3
Hardness
sum of all multivalent cations (primarily Ca2+ and Mg2+), results from water contact with minerals in subsurface environments (leads to scaling)
Total solids
(TS) residue on evaporation = weight of residue/ volume of dried sample
Total suspended solids
(TSS) = weight of residue on filter/volume of filtered sample
Toal dissolved solids
(TDS) = weight of residue from filtrate/volume of dried sample
Total fixed solids
(TFS) = weight of residue after ignition/ original volume of TS sample
TS =
TFS + TVS = TSS + TDS
Turbidity
waters that have suspended solids (generally colloidal) which scatter light
Oxygen solubility in water is highly dependent on…
… temperature (the higher the temperature, the lower the DO cnc) *oxygen solubility also decreases with increasing solute cncs)
Biochemical oxygen demand (BOD)
dissolved oxygen consumed in the biological utilization of the substrate
Chemical oxygen demand (COD)
rapid test, useful for industrial waste waters where toxic compounds inhibit biological activity
Additional WQIs
nutrients, chlorine residual, heavy metals, trace organics
Residence time
time a molecule of water is present in the reactor vessel
Tracer
non-reactive chemical used to determine the hydraulic characteristics of a reactor
Oxidation is used in water treatment to…
… transform soluble Fe2+ and Mn2+ to their insoluble counterparts (can also be achieved using chlorine and potassium permanganate)
Coagulation
Adding chemicals to cause aggregates to form (reduces electrostatic repulsions present in colloidal and particle suspensions)
Aluminum sulfate
(alum) most common coagulant