Unit 5 Notes Flashcards
What are the types of carbohydrate classifications
Simple or complex
What are the simple CHO?
Monosaccharide or disaccharide
What are the types of monosaccharides?
The types of monosaccharides are triose (3-C) like pyruvate, pentose (5-C) like ribose-5-phosphate and hexose (6-C).
What are disaccharides? Name the three types.
Disaccharides are 2 monosaccharides which are bonded together via a glycosidic linkage.
Sucrose = glucose + fructose
lactose = glucose + galactose
Maltose = glucose + glucose
What are the two main disaccharides?
Maltose and lactose
What are the complex CHO?
There are oligosaccharides which are 3-9 monosaccharides bonded together via a glycosidic linkage.
There are polysaccharides which 6 or more monosaccharides joined together via a glycosidic linkage.
What are examples of polysaccharides?
Cellulose, hemicellulose, amylase and amylopectin.
What must sugars have?
Aldehyde or ketone
Where is an aldehyde found?
Where is a ketone found?
An aldehyde is found at the end of the chain.
A ketone is found in the middle somewhere.
What is the difference between a ketone and aldehyde?
A ketone is a carbon with a double bonded O and two side chains.
An aldehyde is a carbon with a double bonded O, one hydrogen and one side chain.
What are sugars with an aldehyde called?
Aldoses
What are sugars with a ketone called?
Ketoses
In summary what must a sugar have (4)?
They need a carbonyl group (C=O), an -OH and either an aldehyde or a ketone.
What allows a sugar to form a ring structure?
Sugars do not require enzymes in order to form a ring structure as the reactivity of the carbonyl group is able to.
What is the difference in shapes between glucose and fructose.
Glucose forms a 6 carbon ring with 1 tail.
Fructose forms a 5 carbon ring with 2 tails.
What carbon in a sugar is referred to as the anomeric carbon?
Regardless if the carbonyl group is attached to an aldehyde or a ketone this is the anomeric carbon. This is the carbon which is apart of the aldehyde or ketone C=O in LINEAR CHAIN.
What are stereoisomers?
These are molecules that are mirror images of each other but canNOT be superimposed on each other.
What molecules have stereoisomerism?
Any molecule which has a chiral carbon which is a carbon with four different side groups attached.
What are the two types of stereoisomers?
Notes: these are molecules which look like mirror images but are not.
There are enantiomers which are mirror images and diastereomers which are NOT mirror images
How can we tell between different stereoisomers easily considering they are mirror images of each other?
We can tell by using the Fischer Projection to see if the greatest chiral carbon has a hydroxyl group on the left (L) or right (D)
How are disaccharides formed?
Disaccharides are formed when the hydroxylated carbons have water removed and become connected via an oxygen. This linkage is known as a glycosidic bond.
Sucrose is composed of both fructose and glucose. What form is glucose in alpha or beta?
What form is fructose in alpha or beta?
Glucose is alpha and fructose is beta.
Is sucrose made more by plants or animals?
Sucrose is more plant formed, to help enhance the sweetness of them to allow for more seed dispersal.
Is fructose made more by plants or animals?
fructose is made more animals.
What form is glucose and galactose found in lactose?
Glucose can be either alpha or beta and galactose can be beta.
Note: alpha = down = right
Beta = up = left
What is different about maltose from the other disaccharides?
What form are the two glucoses in?
maltose is not synthesized to a disaccharide rather it forms through the breakdown of starches during digestion.
The first glucose is alpha and the second glucose is either alpha or beta.
How does maltose form?
When a starch is being broken down what happens is it releases some 2-C units with the carbons being released. Maltose is composed of two glucose molecules held together via a glycosidic bond (two carbons bonded via oxygen).
What is a reducing sugar?
Reducing sugars are a sugar which contains at least one hemiacetal (circle sugar with an aldehyde) that can act as a reducing group in order to join the two monosaccharides together.
Why is sucrose a non-reducing sugar?
Sucrose is a non-reducing sugar because the anomeric both monosaccharides will be used to form the glycosidic bond so not one monosaccharide is acting as the reducing agent.