unit 3 KA4 - equilibria Flashcards
what occurs in a closed system
reversible reactions attain a state of dynamic equilibrium when the rates of forward and reverse reaction are equal
what conditions are required for the reversible reactions to attain a state of dynamic equilibrium
- closed system
- rates of forward and reverse reactions are equal
when do the concentrations of reactants and products remain constant
at equilibrium
is it true that the concentrations of reactants and products remain constant but are rarely equal
yes
how to chemists maximize profits
they employ strategies to move the position of equilibrium in favor of the products
what can be predicted in a given reversible reaction
the effect of altering temperature or pressure or of adding/removing certain reactants/products
what does the addition of a catalyst do
it increases the rates of the forward and reverse reactions equally
what is the relationship between catalysts and equilibrium
catalysts increase the rate at which equilibrium is achieved but do not affect the position of the equilibrium
what effect does increasing temperature in an exothermic reaction have on the position of the equilibrium
it shifts the position to the left because an increase in temperature will lead to the endothermic reaction being favoured
what effect does decreasing the temperature on an exothermic reaction have on the position of the equilibrium
it shifts the positiion to the right because the decreased temperature leads to the exothermic reaction being favoured
what effect does increasing the temperature on an endothermic reaction have on the position of the equilibrium
it shifts the position to the right because the endothermic reaction is favoured
what effect does decreasing the temperature of an endothermic reaction have on the position of the equilibrium
it shifts it to the left because the exothermic reaction is favoured
what effect does increasing the pressure have on a reaction where there are more moles of gas on the right than the left have on the position of the equilibrium
it moves to the left because it favours the side with the less pressure
what effect does decreasing the pressure of a reaction where the products have higher moles of gas than the reactants have on the position of the equilibrium
it shifts to the right because the side with the highest pressure ie the highest moles of gas is favoured
what effect does a catalyst have on the position of the equilibrium
none