unit 3 KA4 - equilibria Flashcards

1
Q

what occurs in a closed system

A

reversible reactions attain a state of dynamic equilibrium when the rates of forward and reverse reaction are equal

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2
Q

what conditions are required for the reversible reactions to attain a state of dynamic equilibrium

A
  • closed system

- rates of forward and reverse reactions are equal

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3
Q

when do the concentrations of reactants and products remain constant

A

at equilibrium

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4
Q

is it true that the concentrations of reactants and products remain constant but are rarely equal

A

yes

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5
Q

how to chemists maximize profits

A

they employ strategies to move the position of equilibrium in favor of the products

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6
Q

what can be predicted in a given reversible reaction

A

the effect of altering temperature or pressure or of adding/removing certain reactants/products

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7
Q

what does the addition of a catalyst do

A

it increases the rates of the forward and reverse reactions equally

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8
Q

what is the relationship between catalysts and equilibrium

A

catalysts increase the rate at which equilibrium is achieved but do not affect the position of the equilibrium

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9
Q

what effect does increasing temperature in an exothermic reaction have on the position of the equilibrium

A

it shifts the position to the left because an increase in temperature will lead to the endothermic reaction being favoured

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10
Q

what effect does decreasing the temperature on an exothermic reaction have on the position of the equilibrium

A

it shifts the positiion to the right because the decreased temperature leads to the exothermic reaction being favoured

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11
Q

what effect does increasing the temperature on an endothermic reaction have on the position of the equilibrium

A

it shifts the position to the right because the endothermic reaction is favoured

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12
Q

what effect does decreasing the temperature of an endothermic reaction have on the position of the equilibrium

A

it shifts it to the left because the exothermic reaction is favoured

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13
Q

what effect does increasing the pressure have on a reaction where there are more moles of gas on the right than the left have on the position of the equilibrium

A

it moves to the left because it favours the side with the less pressure

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14
Q

what effect does decreasing the pressure of a reaction where the products have higher moles of gas than the reactants have on the position of the equilibrium

A

it shifts to the right because the side with the highest pressure ie the highest moles of gas is favoured

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15
Q

what effect does a catalyst have on the position of the equilibrium

A

none

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16
Q

what effect does changing concentration of reactants have on the position of the equilibrium

A

shifts to the right because there are more reactants to turn into products

17
Q

what effect does changing to concentration of products have on the position of the equilibrium

A

it shifts it to the left because there are more products that they want to turn back into reactants