key definitions according to the course specifications Flashcards
groups
vertical columns within the table containing elements with similar chemical properties resulting from a common number of electrons in the outer shell
periods
rows of elements arranged wih increasing atomic number, demonstrating an increasing number of outer electrons and a move from metallic to non-metallic characteristics.
covalent radius
measure of the size of an atom
first ionisation energy
the energy required to remove one mole of electrons from one mole of gaseous atoms
second and subsequent ionisation energies
the energies required to remove further moles of electrons
electronegativity
a measure of the attraction an atom involved in a bond has for the electrons of the bond
covalent bond
a result of two positive nuclei being held together by their common attraction for the shared pair of electrons
polar covalent bonds
formed when the attraction of the atoms for the pair of bonding electrons is differnet
van der waals forces
the intermolecular forces acting between molecules. several different types of these including london dispersion forces, permanent dipole-permanent dipole which include h ydrogen bonding
london dispersion forces
forces of attraction operating between all atoms and molecules. much weaker than all other types of bonding. formed as a result of the electrostatic attraction between temporary dipoles and induced dipoles caused by movement of electrons in atoms and molecules
polar molecule
a moment is described this way if it has a permanent dipole
permanent dipole-permanent dipole interactions
additional electrostatic forces of attraction between polar molecules
hydrogen bonds
electrostatic forces of attraction between molecules that contain highly polar bonds of hydrogen bonded to oxygen, nitrogen or fluorine.
reduction
gain of electrons by a reactant in any reaction
oxidation
loss of electrons by a reactant in any reaction
oxidising agent
a substance that accepts electrons
reducing agent
a substance that donates electrons
the electrochemical series
represents a series of reduction reactions
saturated compounds
ones containing only single C-C bonds
unsaturated compounds
ones containing at least one C=C bond
addition reactions
in these reactions, two molecules combine to form a single molecule
isomers
these are compounds with the same molecular formula but different structural formulae. they may belong to different homologous series and they usually have different physical properties
volatility
ease of evaporation
alcohol
a molecule containing a hydroxyl functional group
primary alcohol
the hydroxyl group is attached to a carbon that has two hydrogens attached to it and 1 carbon
secondary alcohol
hydroxyl group is attached to a carbon that is attached to 2 carbons and a hydrogen
tertiary alcohol
hydroxyl group is attached to a carbon that is attached to 3 other carbons
diols
alcohol containing two hydroxyl groups
triols
alcohols containing three hydroxyl groups
carboxylic acid
a molecule containging the carboxyl functional group
ester
a molecule containing an ester link. these are used as flavourings and fragrances and many have pleasant, fruity smells.
condensation reaction
reaction where two molecules are joined together with the elimination of a small molecule