Unit 3 Chapter 5: Redox reactions Flashcards

1
Q

What is a redox reaction?

A

transfer of electrons; one reactant loses electrons accepted by the other reactant

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2
Q

Oxidation

A

loss of electrons

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3
Q

Reduction

A

gain of electrons

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4
Q

Oxidising agent (oxidants)

A

cause oxidation of another substance (are reduced in the process)

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5
Q

Reducing agent (reductant)

A

cause reduction of another substance (are oxidised in the process)

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6
Q

Metal reactivity series

A
  • represents relative reactivity of metals by listing half-equations involving metals and corresponding cations
  • stronger oxidising agents (more easily reduced) are lower in series
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7
Q

Metal displacement reactions

A

involve transfer of electrons from more reactive metal to positive ions of less reactive ion in solution

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8
Q

Dry corrosion

A

oxidation of a metal by oxygen gas

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9
Q

Wet corrosion

A

oxidation by oxygen gas and water

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10
Q

Oxidation number of a free element

A

0

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11
Q

Oxidation number of a simple ion

A

The charge on the ion

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12
Q

Oxidation number of elements in compounds

A

fixed with exceptions

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13
Q

Oxidation number of main group metals in compound (exception 1)

A

Charge on ions

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14
Q

Oxidation number of hydrogen in compound (exception 2)

A
  • +1 with non-metals

- -1 with metals

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15
Q

Oxidation number of oxygen in compound (exception 3)

A
  • positive in compounds with fluorine

- -1 in peroxides

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16
Q

Oxidation number of halogen in compound (exception 4)

A
  • Fluorine = -1

- Cl, Br, I = -1 except in compounds with oxygen or other halogen above them

17
Q

Sum of oxidation numbers in neutral compound

A

= 0

18
Q

Sum of oxidation numbers of all atoms in polyatomic ion

A

= charge on ion

19
Q

What does the most electronegative element have?

A

negative oxidation number

20
Q

Increase in oxidation number means

A

oxidation has occurred

21
Q

Decrease in oxidation number means

A

reduction has occurred

22
Q

No change in oxidation number means

A

is not a redox reaction

23
Q

Conjugate redox pair

A

an oxidising agent (reactant) and reducing agent (product)

24
Q

Reducing agent (out of 4)

A
  • Loses electrons
  • Reduces oxidising agent
  • Undergoes oxidation
  • Reactant in oxidation half-equation
25
Q

Oxidising agent (out of 4)

A
  • Accepts electrons
  • Oxidises reducing agent
  • Undergoes reduction
  • Reactant in the reduction half-equation
26
Q

Steps for balancing redox half equations (out of 5)

A
  1. Balance all atoms except O and H
  2. Balance O atoms by adding H2O molecules to one side of half-equation
  3. Balance H atoms by adding H+ ions to one side of half-equation
  4. Balance charge on both sides of half-equation by adding electrons to more positive side
  5. Indicate state of substance
27
Q

To construct overall equation from half equations

A

add oxidation half-equation and reduction half-equation (number of electrons used in reduction = electrons released in oxidation)