Unit 3 Chapter 5: Redox reactions Flashcards
What is a redox reaction?
transfer of electrons; one reactant loses electrons accepted by the other reactant
Oxidation
loss of electrons
Reduction
gain of electrons
Oxidising agent (oxidants)
cause oxidation of another substance (are reduced in the process)
Reducing agent (reductant)
cause reduction of another substance (are oxidised in the process)
Metal reactivity series
- represents relative reactivity of metals by listing half-equations involving metals and corresponding cations
- stronger oxidising agents (more easily reduced) are lower in series
Metal displacement reactions
involve transfer of electrons from more reactive metal to positive ions of less reactive ion in solution
Dry corrosion
oxidation of a metal by oxygen gas
Wet corrosion
oxidation by oxygen gas and water
Oxidation number of a free element
0
Oxidation number of a simple ion
The charge on the ion
Oxidation number of elements in compounds
fixed with exceptions
Oxidation number of main group metals in compound (exception 1)
Charge on ions
Oxidation number of hydrogen in compound (exception 2)
- +1 with non-metals
- -1 with metals
Oxidation number of oxygen in compound (exception 3)
- positive in compounds with fluorine
- -1 in peroxides
Oxidation number of halogen in compound (exception 4)
- Fluorine = -1
- Cl, Br, I = -1 except in compounds with oxygen or other halogen above them
Sum of oxidation numbers in neutral compound
= 0
Sum of oxidation numbers of all atoms in polyatomic ion
= charge on ion
What does the most electronegative element have?
negative oxidation number
Increase in oxidation number means
oxidation has occurred
Decrease in oxidation number means
reduction has occurred
No change in oxidation number means
is not a redox reaction
Conjugate redox pair
an oxidising agent (reactant) and reducing agent (product)
Reducing agent (out of 4)
- Loses electrons
- Reduces oxidising agent
- Undergoes oxidation
- Reactant in oxidation half-equation
Oxidising agent (out of 4)
- Accepts electrons
- Oxidises reducing agent
- Undergoes reduction
- Reactant in the reduction half-equation
Steps for balancing redox half equations (out of 5)
- Balance all atoms except O and H
- Balance O atoms by adding H2O molecules to one side of half-equation
- Balance H atoms by adding H+ ions to one side of half-equation
- Balance charge on both sides of half-equation by adding electrons to more positive side
- Indicate state of substance
To construct overall equation from half equations
add oxidation half-equation and reduction half-equation (number of electrons used in reduction = electrons released in oxidation)