Unit 3 Chapter 2: Chemical equilibrium Flashcards

1
Q

Closed system

A

only energy, not matter, is exchanged with the surroundings

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2
Q

Open system

A

both matter and energy exchanged between the system and surroundings

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3
Q

Reversible reaction

A

reaction in which products can react together to be converted back to reactants (shown by a double arrow)

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4
Q

Irreversible reaction

A

reaction in which products cannot react together to be converted back to reactants

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5
Q

Dynamic Equilibrium

A

the point reached by a reversible reaction where the rate of the forward and reverse reaction is equal

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6
Q

Equilibrium can only be achieved in a closed system? Yes or No

A

Yes

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7
Q

Different reactions proceed to different extents therefore?

A

the ratio of reactants to products at equilibrium is different for different reactions

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8
Q

Equilibrium yield

A

indicates how much product is formed at equilibrium

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9
Q

Reaction rate

A

measure of the change in the concentrations of the reactants and products with time

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10
Q

Le Chatelier’s principle

A

if an equilibrium system is subject to change, the system will shift to partially oppose the change

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11
Q

Adding more reactant causes:

A

Equilibrium shift to the products

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12
Q

Adding more product causes:

A

Equilibrium shifts to the left

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13
Q

Decreasing pressure (increasing volume) causes:

A

Equilibrium shifts in direction of most particles

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14
Q

Adding inert gas (constant volume) causes:

A

No change

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15
Q

Adding water (dilution of solution) causes:

A

Shifts in direction of most particles

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16
Q

Increasing temperature (exothermic) causes:

A

Equilibrium shifts towards the reactions

17
Q

Increasing temperature (endothermic) causes:

A

Equilibrium shifts towards the products

18
Q

Adding a catalyst causes:

A

No change

19
Q

Equilibrium constant (Kc):

A

The constant for a particular chemical reaction at a particular temperature; provides a measure of the extent of reaction and the relative concentrations of reactants and products at equilibrium

20
Q

Kc > 10^4

A

almost complete reaction occurs

21
Q

Kc < 10^-4

A

negligible reaction occurs

22
Q

Kc =

A

[P]/[R]

23
Q

Reaction quotient (Qc):

A

can be calculated for any stage of a chemical reaction

24
Q

Qc < Kc

A

reaction must shift to the right to reach equilibrium

25
Q

Qc = Kc

A

reaction has reached equilibrium

26
Q

Qc > Kc

A

reaction must shift to the left to reach equilibrium