Unit 3 Chapter 3: Equilibrium in acid base chemistry Flashcards
Bronsted-Lowry acid:
proton donor
Bronsted-Lowry base:
proton acceptor
Conjugate base:
formed by an acid when it donates a proton
Conjugate acid:
formed by a base when it accepts a proton
Conjugate acid-base pair:
molecules or ions that differ by a H+ ion
Amphiprotic:
substance that can act as an acid or base
Monoprotic:
can only donate one proton
Polyprotic acid:
can donate more than one proton to a base
o First dissociation of a polyprotic acid occurs to a greater extent than those following. The extent decreases with each dissociation
Properties of acids (out of 8):
- turns litmus indicator red
- corrosive
- sour
- react with bases
- low pH < 7
- donate H+
- dissociate to produce hydronium (H+)
- conduct electric current in solution
Properties of bases (out of 8):
- turns litmus indicator blue
- caustic, slipper
- bitter
- react with acids
- high pH > 7
- accepts H+
- dissociate to produce hydroxide (OH-)
- conduct electric current in solution
Concentrated acid/base:
contains more moles of solute per litre than a dilute acid/base
Strong acid/strong bases:
more readily accept/receive protons than weaker acids/bases
Stronger acid =
weaker conjugate base
Stronger base =
weaker conjugate acid
Strong acid examples (out of 2):
- Hydrochloric acid
- Sulfuric acid
Weak acid examples (out of 2):
- Ethanoic acid
- Phosphoric acid
Strong base examples (out of 2):
- Sodium hydroxide
- Potassium hydroxide
Weak base example (out of 1):
- Ammonia
Self-ionisation of water equation:
H2O + H2O <=> H3O+ + OH-
Ionic product for water:
Kw = [H3O+][OH-] = 1.00 x 10^-14
pH < 7:
acidic solution
pH = 7:
neutral solution
pH > 7:
basic (alkaline solution)
Number of moles of acid/base in solution does not or does change during dilution?
Does not
Acidic solution is diluted:
pH increases
Basic solution is diluted:
pH decreases
Buffer:
solutions that resist change in pH when a small amount of acid/ base is added
Acidic Buffer solution:
formed by reacting weak acid, salt of the acid, and strong base
Alkaline buffer solution:
formed by reacting weak base, salt of base, and strong acid
Equilibrium expression for dissociation of monoprotic acid in water:
HA(aq) <=> H+(aq) + A-(aq)
Equation for Ka=
Ka = [H+][A-]/[HA]
Equation for Kb=
Kb = [NH4+][OH-]/[NH3]
Acidity constant (Ka) measures:
strength of an acid
Dissociation constant for base (Kb) measures:
strength of a base
Indicator:
solutions of weak acid or base in solution with conjugate acid and base that change colour when pH = pKa
Equivalence point:
point in titration when reactants have reacted in correct mole ratios
End point:
point during titration where indicator changes colour