Unit 3 Chapter 3: Equilibrium in acid base chemistry Flashcards

1
Q

Bronsted-Lowry acid:

A

proton donor

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2
Q

Bronsted-Lowry base:

A

proton acceptor

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3
Q

Conjugate base:

A

formed by an acid when it donates a proton

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4
Q

Conjugate acid:

A

formed by a base when it accepts a proton

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5
Q

Conjugate acid-base pair:

A

molecules or ions that differ by a H+ ion

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6
Q

Amphiprotic:

A

substance that can act as an acid or base

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7
Q

Monoprotic:

A

can only donate one proton

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8
Q

Polyprotic acid:

A

can donate more than one proton to a base
o First dissociation of a polyprotic acid occurs to a greater extent than those following. The extent decreases with each dissociation

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9
Q

Properties of acids (out of 8):

A
  • turns litmus indicator red
  • corrosive
  • sour
  • react with bases
  • low pH < 7
  • donate H+
  • dissociate to produce hydronium (H+)
  • conduct electric current in solution
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10
Q

Properties of bases (out of 8):

A
  • turns litmus indicator blue
  • caustic, slipper
  • bitter
  • react with acids
  • high pH > 7
  • accepts H+
  • dissociate to produce hydroxide (OH-)
  • conduct electric current in solution
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11
Q

Concentrated acid/base:

A

contains more moles of solute per litre than a dilute acid/base

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12
Q

Strong acid/strong bases:

A

more readily accept/receive protons than weaker acids/bases

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13
Q

Stronger acid =

A

weaker conjugate base

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14
Q

Stronger base =

A

weaker conjugate acid

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15
Q

Strong acid examples (out of 2):

A
  • Hydrochloric acid

- Sulfuric acid

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16
Q

Weak acid examples (out of 2):

A
  • Ethanoic acid

- Phosphoric acid

17
Q

Strong base examples (out of 2):

A
  • Sodium hydroxide

- Potassium hydroxide

18
Q

Weak base example (out of 1):

19
Q

Self-ionisation of water equation:

A

H2O + H2O <=> H3O+ + OH-

20
Q

Ionic product for water:

A

Kw = [H3O+][OH-] = 1.00 x 10^-14

21
Q

pH < 7:

A

acidic solution

22
Q

pH = 7:

A

neutral solution

23
Q

pH > 7:

A

basic (alkaline solution)

24
Q

Number of moles of acid/base in solution does not or does change during dilution?

25
Acidic solution is diluted:
pH increases
26
Basic solution is diluted:
pH decreases
27
Buffer:
solutions that resist change in pH when a small amount of acid/ base is added
28
Acidic Buffer solution:
formed by reacting weak acid, salt of the acid, and strong base
29
Alkaline buffer solution:
formed by reacting weak base, salt of base, and strong acid
30
Equilibrium expression for dissociation of monoprotic acid in water:
HA(aq) <=> H+(aq) + A-(aq)
31
Equation for Ka=
Ka = [H+][A-]/[HA]
32
Equation for Kb=
Kb = [NH4+][OH-]/[NH3]
33
Acidity constant (Ka) measures:
strength of an acid
34
Dissociation constant for base (Kb) measures:
strength of a base
35
Indicator:
solutions of weak acid or base in solution with conjugate acid and base that change colour when pH = pKa
36
Equivalence point:
point in titration when reactants have reacted in correct mole ratios
37
End point:
point during titration where indicator changes colour