Unit 3 Flashcards

Halogens

1
Q

What do Halogens form when they react with metals?

A

Salts

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2
Q

Can all halogens exist as diatomic molecules?

A

Yes they can covalently bond with each other

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3
Q

Are halogens metals?

A

No, so they cant conduct electricity

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4
Q

Are halogens good oxidising agents or reducing agents

A

Oxidising agents, Remove electrons form other species have large electron affinity

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5
Q

What happens to the melting/B points as you go down the halogen group?

A

They increase due to increased mass. More van der waals forces

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6
Q

What property do bromine and iodine have?

A

They are both volatile ( low boiling point, vaporize easily). All halogens are volatile its just bromine and iodine are solids, the rest are gasses naturally

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7
Q

Iodine goes through a process of sublimation, what does this mean?

A

When heated it goes straight from a solid to a gas

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8
Q

Why does reactivity decrease down the halogen group?

A

Because the further down you go means more energy levels (shells) which means it is harder to attract another electron

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9
Q

What is a displacement reaction?

A

When an element replaces another in the reaction if it is more reactive. So a metal can replace another metal in a metal oxide if it is more reactive and make its own oxide

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10
Q

What does fluorine do to water?

A

Oxidises it so that it forms oxygen and ozone

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11
Q

What do chlorine and bromine do to water?

A

They make it an acidic solution

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12
Q

What does iodine do in water?

A

It is insoluble, but can be dissolved if there are other iodide ions

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13
Q

How do all of the halogens react with hydrogen?

A

They form covalent bonds.
Fluorine will explode with H
Chlorine will produce chloride gas if there is a flame
bromine will give hydrogen bromide gas
Iodine will only partially combine. an equilibrium is set up

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14
Q

Why does HF have a really high boiling point?

A

There’s H-bonding

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15
Q

Which halogens are strong acids and why?

A

All except HF are strong acids as they easily donate a proton.

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16
Q

Why is HF a weak acid?

A

Ions formed from dissociating the proton (h30+ and F-) are so strongly attracted to each other that they bind, H3O needs to be free in order to be acidic

17
Q

What is a disproportionation reaction?

A

One in which an element is both oxidised and reduced at the same time. it produces two products

18
Q

inter halogens are halogen atoms bonded to a different halogen atom. Are they polar?

A

Yes due to difference in electronegativity

19
Q

Electron electron repulsion sequence?

A

LP-LP> LP-BP>BP-BP

20
Q

How do you work out the shape of a compound? AX

A

1) find central atom (A) usually least electronegative
2) Find #of valence electrons in A
3) Count electrons used by other atoms to form bonds
4) is positive ion -1. If negative ion +1
5) add numbers found from steps 2 3 and 4 divide by 2
6) if molecule has double bonds subtract 1
look at the table

21
Q

What is a cation?

A

Positively charged ion

22
Q

What are the halogen oxides good at?

A

Oxidising

23
Q

How are oxoacids of halogens formed?

A

Reacting halogens with their oxides and water. The number of oxygens added the stronger the acid.

24
Q

Why would acidity decrease along with electronegativity?

A

As the more electronegative an element the better it is at pulling electrons towards itself making it easier for H+ to be donated. (the more O’s in a oxoacid the more electronegative)

25
Q

Hydrogen oxidation number?

A

+1 . if bonded to a metal -1

26
Q

Oxygen oxidation number?

A

-2

27
Q

Fluorine oxidation number?

A

-1

28
Q

What is a redox potential?

A

The tendency of species to be reduced against an electrode with potential value of 0. Reagent with the highest redox potential will be oxidising

29
Q

What are pseudo halogens and halides?

A

they mimic the chemistry of halogens and halides

30
Q

What noble gas was used in lights and could emit a blue glow?

A

Xenon

31
Q

What state at the halogens in?

A

First two are gasses bromine is a liquid the rest are solids