Unit 2 - Vinification Flashcards
EU definition of “wine”?
the product obtained exclusively from the total or partial alcoholic fermentation of fresh grapes, whether or not
crushed, or of grape must
Grape maturity?
One of the most decisive factors in determining wine quality and style
Physiological changes - phenolics & taste
Biochemical changes - sugars & acids
Key questions for harvesting?
When
Forecasting
Preparing
How (manual vs machine)
Harvest date?
Grape ripeness
- sugar
- acid
- health
- phenolic ripeness
Agrochemicals (fungicides, insecticides, herbicides, pesticides, etc)
- withholding period
- fermentation and health problems
e.g. sulphur –> hydrogen sulphide
copper –> brown haze, toxic copper salts in wine
Weather
- rain –> dilution, grape swelling and bursting
- hail
Availability of resources (human and mechanical)
Legal restrictions
Havesting - Getting ready?
Estimating the crop (sufficient tank space)
Checking & cleaning equipment and machinery
Tanks clean and ready for use
Oenological products (yeasts, sulphur, enzymes, etc)
Havesting - Machine vs Hand Factors to consider?
Factors to consider
- quality
- speed
- economics
- feasibility
Machine Harvesting Pros and Cons?
Machine
- speed, grapes at peak; cheaper labour costs; cool night
- damage, oxidation, no selection, cost of machinery, flat land, trellis system (no bush nor pergolas)
Hand Harvesting Pros and Cons?
Manual
- less damage, more selectivity, slopes, less $ for equipment
- high labour costs (10X machine), slower
- for sparkling wine, carbonic maceration (whole bunches); Tokaji, Beerenauslese, Trockenbeerenauslese
(selection of grapes); required by law
Havesting - Transport & Reception?
Use shallow picking containers Less transfer between containers Less dumping heights Refrigerated trucks Minimize delay before processing
Oxidation
- browning, loss of aroma
- CO2/nitrogen blanket; potassium metabisulphite; harvest at night; min delay
Microbial growth
- eliminate rotten grapes; clean equipment; berry integrity; min delay
Contamination
- rain
- leaves & stalks
- MOG (material other than grape)
- soil
Key questions for grape processing?
Sorting De-stemming Crushing Type of press Amount of SO2 Must treatments
Sorting in French?
Triage
De-stemming?
Tannin control and ease of processing
Egrappoir = de-stemming machine
Most grapes are de-stemmed
Not for sparkling wines and carbonic maceration
Not required for machine harvested grapes
De-stemming Pros?
Pros
- prevent release of phenolics, herbaceous flavours, MOG
- more efficient pressing
- remove water and potassium (absorb colour and alcohol)
De-stemming Cons?
Cons
- whites: slower pressing and drainage (not for fine wines)
- reds: compaction of pomace cap; tannins and colour
Crushing?
Release free-run juice
Reduce the solid parts of the grape to the correct condition for fermentation and maceration
Increase extraction of tannin and colour
Careful not to damage grape seeds
Not to crush for semi-carbonic maceration (Spain, Beaujolais, Languedoc-Roussillon for Carignan
and Grenache)
Fouloir?
crusher
Crushing Equipment?
Equipment
- foot or de-stem/crush
- heat exchanger
- SO2 to reduce oxidation and prevent microbial spoilage
- use of pectolytic enzymes to release more juice
Pressing?
Use of minimum pressure
Done at grape reception for whites; after fermentation for reds
70% of the total weight
Skin contact for aromatic whites (Sauvignon Blanc, Semillon, Muscat, Riesling, Gewuztraminer, Viognier)
- 5-10 C
- few to 24 hours
- pectolytic enzyme
Finest aromatic wines
- very gentle whole-bunch pressing
- no skin contact
Types of press?
Vertical screw press (basket press) Horizontal screw press (e.g. Vaslin) Pneumatic press (e.v. Willmes) Tank press (pneumatic press with inert gas) Continuous screw press
Vertical screw press (basket press)?
Vertical screw press (basket press)
- simple and easy; clear must or wine
- slow, labour intensive; extraction of bitter phenolics; oxidation
- high-class wineries; champagne
Horizontal screw press (e.g. Vaslin)?
Horizontal screw press (e.g. Vaslin)
- more efficeint in terms of time and labour; simple; can be automated; prevent oxidation with inert gases
- rather coarse juice; extraction of bitter phenolics; high pressure reduces quality
Pneumatic press (e.v. Willmes)?
Pneumatic press (e.v. Willmes)
- low pressure; good extraction; less bitter phenolics; high quality juice
- very slow
Tank press (pneumatic press with inert gas)?
Tank press (pneumatic press with inert gas)
- no oxygen contact; high quality juice
- very slow; costly
Continuous screw press?
Continuous screw press
- high throughput; less labour-intensive and time consuming
- poor quality; bitter phenolics
Must Treatments?
Before fermentation SO2 Clarification Enrichment or Chaptalisation Must concentration De-acidification Acidification Tannin Bentonite Flavour and colour enhancing enzymes Oxygen
SO2 (Sulfur dioxide) in winemaking?
Prevent oxidation and premature fermentation
Kill bacteria (for whites)
Stun weaker yeasts
Improve extraction of polyphenols from skins (for reds)
Four properties of SO2 (Sulfur dioxide) in winemaking?
Four properties:
Antiseptic - kills microorganisms (acetobacter/wild yeasts)
Antioxidant - binds with oxygen
Antioxidasic - denatures oxidasic enzymes
Combines with acetaldehyde (by-product of oxidation)
Four forms of SO2?
potassium metabisulphate powder
compressed and liquidified SO2 gas
SO2 in solution (5%)
Burning sulphur tablets or candles
SO2 levels?
Based on style of wine, health of grapes, pH
Lower for organic wines
Recommeded -
White: 60-100 mg/l
Red: 10-60 mg/l
Limits -
Dry white: 200 mg/l
Dry red: 150 mg/l (red wines contain natural anti-oxidants)
Off-dry white (5g/l sugar): 250 mg/l
BA/TBA/Sauternes: 390 mg/l (binding power of sugars)
Free, bound and total SO2?
Free - active, protective, molecular SO2 & sulphurous acid
Bound - combined with sugars, aldehydes, ketones, inactive
Total - free + bound
Pre-fermentation clarification?
Remove solid particles
Produce cleaner flavours, more finesse, less bitter
Depend on
- state of the harvest
- grape processing method
- wine style required (little for full-bodied, complex wines; more for delicate and highly aromatic wines)
Clarification methods?
Cold settling (common)
Centrifugation
Diatomaceous earth filtration
Flotation
Clarification method - Cold settling?
Cold settling (common)
- debourbage
- by gravity
- 12 to 24 hours
- cool temperature (5-10 C)
- clear must racked off the sediment (lees)
- pectolytic enzymes and SO2
Clarification method - Centrifugation?
Centrifugation
- high level of clarity
- harsh, high risk of oxidation, expensive
- large wineries
Clarification method - Diatomaceous earth filtration?
Diatomaceous earth filtration
- for aromatic grapes
- can strip the must of nutrients for fermentation
Clarification method - Flotation?
Flotation
- bubbling small amounts of N, CO2 or air
- catching and floating solid particles
- skimmed off by a rotary suction device
- large wineries or cooperatives
Enrichment?
Adding sugar to increase potential alcohol
No effect on wine sweetness
Permitted in cool regions
Unusually cool summer or early harvest in warm regions
Not allowed in Italy/Spain
Forms of sugar for enrichment?
Sucrose (beet sugar) or cane sugar - chaptalisation
RCGM (rectified concentrated grape must) - enrichment
1 kg of sugar increase vol of wine by 0.63 l
White: 1% abv require 17 g/l sugar
Red: 1% abv require 19 g/l sugar (evaporation due to higher fermentation temp & pumping over)
Must concentration techniques?
Vacuum evaporation
Reverse osmosis
Cryoextraction
Vacuum evaporation?
Vacuum evaporation
- water evaporates at low temperature of 20 C
- loss of aromas, hence use of chilled aroma trap
Reverse osmosis?
Reverse osmosis
- high pressure applied to must against a membrane filter
- no loss of aromas
- also used to remove alcohol and volatile acididty
Cryoextraction?
Cryoextraction
- chill grapes to remove water in from of ice
- no loss of aromas
EU Rules on enrichment?
Wine must be > 8.5% alcohol
Enriched wine 2% or reduce vol by 20% (whichever is lower)
Only one enrichment method and no blending of differently enriched wines
Potential alcohol?
alcohol level that would result if all sugars are fermented
Actual alcohol?
actual alcohol level after fermentation
Residual sugar?
unfermented sugars (natural or added) left in the wine expressed as g/l or %
Total alcohol?
actual alcohol + potential alcohol from residual sugar
Natural alcohol?
total alcohol in an un-enriched must or wine
De-acidification?
Tartaric acid cannot be reduced by > 1 g/l
Not permitted in warmest regions - CIII(b)
Increase pH, therefore risk of microbial infection and decrease effectiveness of SO2
De-acidification methods (Tartaric only)?
Tartaric only
- potassium bicarbonate (potassium tartrate crystals)
- calcium carbonate (leaves high level of calcium tartrate)
De-acidification methods (Malic only)?
Malic only
- malolactic fermentation
De-acidification methods (Both tartaric and malic)?
Both tartaric and malic
- double-salt de-acidification
- Acidex (specifially prepared calcium carbonate with small amount of calcium tartrate-malate)
- calcium tartrate-malate crystals
Acidification?
"buffering" effects logorithmic pH scale - more acid to alter pH from 3.2 to 3.0 than from 3.8 to 3.6 CII and CIII zones Not in Rhone
Tartaric acid for acidification
- 1.5 g/l in must; 2.5 g/l in wine
Citric acid
- 1 g/l in must
- never added before fermentation
- metabolised by yeast and bacteria to form acetic acid
Tannin?
Added before fermentation
Protection from oxidation
Stablilize colour
Improve mouth feel
Bentonite?
Fining agent in form of clay
Remove proteins
Non-selective and remove flavour compounds
Flavour and colour enhancing enzymes?
Aid juice extraction Optimise extraction of aroma precursors Improve colour extraction Increase efficiency of settling Developed from fungi Added at crushing
Use of oxygen in winemaking?
Hyperoxidation
Development of yeasts at start of fermentation
Revitalization of yeast
Micro-oxygenation of harsh polyphenols in barrels
Anaerobic maturation after bottling (not for screwcaps)
Add complexity and character in anaerobically made wines
Oxidases?
Laccase
- grey rot
- SO2 resistant
- pasteurisation (heating must to 65-70 C)
Tyrosinase
- controlled by SO2
Copper and iron
Reductive (anaerobic) handling?
Minimize exposure to oxygen
SO2
Low temperatures
Inert gases used to flsuh out presses, pipes, vats
Reductive taint - sulphur dioxide becomes hydrogen sulphide
Oxidative (Aerobic) handling?
Minimal use of SO2
Controlled exposure to oxygen
Develop complex flavours and aromas
Enzymatic oxidation of phenolics is encouraged
Form insoluble polymers removed by clarification
More stable wine
Production of oloroso Sherry, tawny Port, vin jaune from the Jura, some Tokaji
Hyperoxidation?
Bubbling air through the juice
Colour stabilisation in white wines
Can decrease aromalics (e.g. Sauvignon Blanc)
Effects of excessive oxygen?
Acetaldehyde (ethanal) –> flat sherry-like flavour
Bitter-tasting components from oxidation of phenolics
Spoilage bacteria, e.g. acetic bacteria
Ascorbic acid?
Vitamin C
Antioxidant
No antiseptic effect
Used without SO2 –> hydrogen peroxide (bleaching agent)
Alcoholic fermentation?
glucose/fructose + yeasts –> ethanol + CO2 + energy
180 g sugar –> 92 g alcohol + 88 g CO2
Saccharomyces yeast
16-18 g/l sugar needed to produce 1% abv (8 g/l)
Glucose
- dominant early in ripening process
- yeast prefer glucose
Frutose
- dominant in very ripe grapes
- late harvest or botrytis-affected grapes
- difficult to ferment fructose-rich grape must to dry wine
Rate of fermentation?
Concentration of sugars Availability of oxygen Temperature Type and quantity of yeasts Nutrient content of the must SO2
Fermentation ceases?
All sugar consumed Alcohol reaches 15% killing yeasts Increasing pressure of CO2 to 7 atmospheres Chilling to low temperature (5 C) SO2 Pasteurisation (80 C for a few second) Removing yeasts (filtration, centrifuge) Fortification with spirit
By-products of fermentation?
Glycerol (Glycerine) - smoothness and weight of wine Acetaldehyde Ethyl acetate (nail polish) Aroma esters Fusel oils, e.g. methanol
Fermentation vessels?
Stainless steel tanks
Wooden fermentation vessels
Cement tanks
Stainless steel tanks?
Stainless steel tanks
- easy to clean and maintain
- allow temperature control
- rotofermenters