Unit 2: Section 1 - Periodicity CDS * Flashcards
periodicity
what do all the elements in a period have?
they all have the same number of electron shells
what do all the elements in a group have?
they all have the same number of electrons in their outer shell so they all have similar properties
what does the group number tell you?
the number of electrons in the outer shell
what happens to the atomic radius across a period?
same shells same shielding more protons stronger electrostatic forces of attraction between nucleus and outer electrons atomic radius decreases
why does the atomic radius decrease with more protons?
the stronger the positive charge, the more the outer electrons are pulled towards the nucleus, making the atom smaller. (greater charge density)
what happens to melting points across a period?
they vary as they depend on the structure and bonding of the elements.
which types of bonding of elements have the highest and lowest melting points?
giant covalent lattice - highest
metallic
simple molecular - lowest
what happens to the melting points of metals across a period?
more protons
more delocalised electrons
stronger electrostatic forces of attraction
melting point increases
why does silicon have the highest melting point in period 3?
its macromolecular, with a tetrahedral structure. many strong covalent bonds link atoms together
a lot of energy is required to break these bonds
what happens to the melting points of molecular substances across a period?
it depends on the number of atoms in the molecule.
the more atoms
the more electrons
the stronger van der Waals forces between molecules
the higher the melting point
what happens to ionisation energy across a period?
ionisations generally increase across a period:
more protons
stronger electrostatic forces of attraction
the more energy required to remove an electron
what happens to ionisation energy between group 2 and 3?
the outer electron is in a new orbital - p1 compared to s2.
in a higher energy level
so ionisation energy lower
what happens to ionisation energy between group 5 and 6?
the outer electron is sharing a sub-shell with another electron in p4
repulsion between electrons
lower ionisation energy
what happens to atomic radius down a group?
more shells
more shielding
weaker electrostatic forces of attraction
atomic radius increases
what happens to ionisation energy down a group?
more shells
more shielding
weaker electrostatic forces of attraction
ionisation energy decreases