Unit 2: Section 1 - Periodicity CDS * Flashcards

periodicity

1
Q

what do all the elements in a period have?

A

they all have the same number of electron shells

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2
Q

what do all the elements in a group have?

A

they all have the same number of electrons in their outer shell so they all have similar properties

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3
Q

what does the group number tell you?

A

the number of electrons in the outer shell

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4
Q

what happens to the atomic radius across a period?

A
same shells
same shielding
more protons
stronger electrostatic forces of attraction between nucleus and outer electrons
atomic radius decreases
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5
Q

why does the atomic radius decrease with more protons?

A

the stronger the positive charge, the more the outer electrons are pulled towards the nucleus, making the atom smaller. (greater charge density)

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6
Q

what happens to melting points across a period?

A

they vary as they depend on the structure and bonding of the elements.

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7
Q

which types of bonding of elements have the highest and lowest melting points?

A

giant covalent lattice - highest
metallic
simple molecular - lowest

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8
Q

what happens to the melting points of metals across a period?

A

more protons
more delocalised electrons
stronger electrostatic forces of attraction
melting point increases

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9
Q

why does silicon have the highest melting point in period 3?

A

its macromolecular, with a tetrahedral structure. many strong covalent bonds link atoms together
a lot of energy is required to break these bonds

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10
Q

what happens to the melting points of molecular substances across a period?

A

it depends on the number of atoms in the molecule.
the more atoms
the more electrons
the stronger van der Waals forces between molecules
the higher the melting point

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11
Q

what happens to ionisation energy across a period?

A

ionisations generally increase across a period:
more protons
stronger electrostatic forces of attraction
the more energy required to remove an electron

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12
Q

what happens to ionisation energy between group 2 and 3?

A

the outer electron is in a new orbital - p1 compared to s2.
in a higher energy level
so ionisation energy lower

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13
Q

what happens to ionisation energy between group 5 and 6?

A

the outer electron is sharing a sub-shell with another electron in p4
repulsion between electrons
lower ionisation energy

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14
Q

what happens to atomic radius down a group?

A

more shells
more shielding
weaker electrostatic forces of attraction
atomic radius increases

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15
Q

what happens to ionisation energy down a group?

A

more shells
more shielding
weaker electrostatic forces of attraction
ionisation energy decreases

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