Unit 2 - Esters, Fats and Oils Flashcards

1
Q

What are esters defined as

A

molecules that contain the ester link -COO

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2
Q

what two types of molecule make up an ester?

A

an alcohol and carboxcylic acid

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3
Q

what is the reaction called that forms an ester?

A

a condensation reaction

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4
Q

condensation reaction

A

is where the two molecules join together with the elimination of a smaller molecule

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5
Q

in a condensation reaction what is the small molecule that is eliminated?

A

water molecule

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6
Q

what catalyst is normally used to speed up the reaction?

A

concentrated sulphuric acid

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7
Q

what is a condensation reaction making an ester also known as

A

estrification

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8
Q

explain what happens to the structure of the alcohol and carboxcyclic acid in a condensation reaction

A

the OH from the carboxyclic acid and the H from the OH in the alcohol break off to form a water molecule. The remaining parts join to form the ester link.

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9
Q

what does the catalyst do other than speed up the reaction

A

it increases the yield of the ester produced.

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10
Q

what is the functional group of an ester.

A

O
=
R - C - O - R

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11
Q

hydrolysis reaction

A

where a molecule is broken up using the elements of water, allowing it to be hydrolysosed back into the alcohol and carboxcylic acid it came from

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12
Q

example of when hydrolysis occurs naturally

A
  • Perfumes going off
  • Acetone hydrolysing into ethanoic acid
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13
Q

what is the practical technique we can use to carry out hydrolysis

A

heating under reflux

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14
Q

why does water flow through the bottom in a condenser

A

this is because there are likely to be air pockets which will result in poor condesation if it enters from the top.

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15
Q

why are anti-bumping granules used?

A

becuase they are inert and help the mixure boil more smoothly.

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16
Q

what catalysts can be used in this reaction?

A
  • Strong acid (H+ Ions) called acid hydroylsis.
  • Strong Alkali (OH- Ions) called alkali hydrolysis
17
Q

why is alkali hydrolysis better?

A

becuase it produces the alcohol and the salt of the carboxcyclic acid as the acid formed is immediately neutralised by the alkali.

18
Q

proply ethanoate + water —-(Sodium Hydroxide)—>

A

propanol + sodium ethanoate

19
Q

examples of uses for esters

A
  • nail varnish
  • perfumes
  • artificial fruit flavourings
20
Q

features of esters

A
  • volatile
  • low polarity
  • contain the ester link -COO
21
Q

what alcohol are the esters of fats and oils made from?

A

glycerol

22
Q

what is the difference between fats and oils?

A

their state at room temperature: fats are solid oils are liquid.

23
Q

why are fats and oils so important for us?

A
  • Fats and oils are a concentrated source of energy .
  • Essential for the transport and storage of fat soluble vitamins in the body
24
Q

example of animal , plant and marine fats/oils

A

Lard, olive oil, fish oil

25
Q

what can be used to test for unsaturation in fats and oils

A

bromine solution

26
Q

what experimental procedure can be used to determine the degree of unsaturation in edible fats

A

titration of bromine water into the fat/oil

27
Q
A