Unit 2 Bonding Flashcards
Define delocalized electron
A valence electron that is able to roam freely among cations in a lattice structure
What are the metallic properties?
- Conductivity of electricity
- Malleable
- Ductile
Define malleable
reshape under pressure
Define ductile
Drawn into a thin wire
What is a cation?
A positive ion
What is an anion?
A negative ion
What is an Ionic Bond?
A bond between a metal and a non-metal
How do you name Ionic Compounds?
the ending of the compound ends in “-ide”
What physical properties will the crystal lattice structure influence?
- Texture
- Melting and Boiling points
- Volatility
- Conductivity
- Solubility
Define volatility
Rate of evaporation
What is the characteristic of non-polar covalent bonds?
No electronegativity difference
What is the characteristic of polar covalent bonds?
slight electronegativity difference (less than 1.8)
What is the name for NO3^-
nitrate
What is the name for OH^-
hydroxide
What is the name for SO4^2-
sulfate
What is the name for CO3^2-
carbonate
What is the name for PO4^3-
phosphate
What is the name for HCO3^-
bicarbonate/hydrogen carbonate
What is the name for NH4^+
ammonium
What is the prefix for 1?
mono
What is the prefix for 2?
di
What is the prefix for 3?
tri
What is the prefix for 4?
tetra
What is the prefix for 5?
penta
What is the prefix for 6?
hexa
What is the prefix for 7?
hepta
What is the prefix for 8?
octa
What is the prefix for 9?
nona
What is the prefix for 10?
deca
What is the name for H2O?
water
What is the name for CH4?
methane
What is the name for NH3?
ammonia
What are the allotropes of Carbon?
- Diamond
- Graphite
- Buckminsterfullerene
What are the characteristics of a diamond?
- one carbon atom is covalently bonded to four other carbons
- Bonds are shared equally
- very hard and high melting point
- formed under high pressure but don’t last forever
What are the characteristics of graphite?
- Organized into layers of hexagonal rings
- one carbon is strongly bonded to three other carbons within the layer
- very weak bonds between carbons in layers above and below
When was buckminsterfullerene discovered?
1985
What are the characteristics of buckminsterfullerene?
Consists of 60 carbons arranged in hexagons and pentagons (similar to a soccer ball pattern)
What new branch of science did the buckminsterfullerene lead to?
Nanotechnology
What does VSEPR Theory stand for?
Valence Shell Electron Pair Repulsion
What does symbol “E” represent in the VSEPR Theory?
lone pair
What does symbol “A” represent in the VSEPR Theory?
Central atom
What does symbol “B” represent in the VSEPR Theory?
Bonded atoms
State the shape and the bond angle for the formula AB(E)n
Shape: Linear
Bond angle: N/A
State the shape and the bond angle for the formula AB2
Shape: linear
Bond angle: 180°
State the shape and the bond angle for the formula AB3
Shape: Triginal Planar
Bond angle: 120°
State the shape and the bond angle for the formula AB4
Shape: Tetrahedral
Bond angle: 109.5°
State the shape and the bond angle for the formula AB2E
Shape: Angular
Bond angle: 120° > x > 90°
State the shape and the bond angle for the formula AB2E2
Shape: Angular
Bond angle: 109.5° > x > 90°
State the shape and the bond angle for the formula AB3E
Shape: Trigonal Pyramidal
Bond angle: 109.5° > x > 90°
What are the steps for determining the shape and bond angle using the VSEPR Theory?
1) Draw out electron dot diagram
2) Count the bonded and lone pair electrons around the central atom
3) Write out the general formula
4) State the shape and the bond angle
What is a central atom?
The atom with the most bonding spots
What are the types of dipoles?
Permanent and temporary/induced
What criteria must be met in order for a molecule to be polar?
1) It must have at least one polar bond
2) The arrangement of the bonds must be asymmetric. Central atom has either: a) lone pair of electrons and/or b) different atoms bonded to it
What type of attractive forces do non-polar molecules have?
only London Dispersion forces
What is the strongest intermolecular force?
Hydrogen bonding
Define intermolecular force and give an example
The attraction force between molecules
ex. hydrogen bonding between two molecules of water
Define intramolecular forces and give an example
The attraction force between to atoms within a molecule
ex. ionic or covalent bonds
When will London Dispersion Forces become stronger?
When:
- molar mass of molecule increases
- length of chained molecule increases
What are the three elements that can from a Hydrogen bond?
Fluorine, oxygen, or nitrogen