unit 1a: shapes of molecules Flashcards
shared electrons in a covalent charge
negatively charged so they repel the electrons in other bonds in a molecule
particular shapes in molecules because
they try to minimise repulsive forces
VSEPR
valence shell electron pair repulsion
five basic shapes depending on the number of electron pairs
linear, trigonal planar, tetrahedral, trigonal bipyramidal, octahedral
dative bond
when both electrons come from the same atom
bonding pairs
electrons pairs involved in bonding
non-bonding pairs
these have a greater repulsive effect than bonding pairs so their presence in a molecule causes slightly distorted shapes
determining if there are non-bonding pairs
subtract the number of atoms around the central atom from the number of electron pairs, any left over must be non-bonding
linear bond angles
180°
trigonal planar bond angles
120°
tetrahedral bond angles
109.5°
trigonal bipyramidal bond angles
120° and 90°
octahedral bond angles
90°
3 bonding 1 non-bonding
trigonal pyramidal, 107°
2 bonding 2 non-bonding
angular, 105°