unit 1a: atomic orbitals and quantum numbers Flashcards

1
Q

quanta

A

the fixed amount of energy possessed by electrons within atoms

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2
Q

electrons behave as

A

standing (stationary) waves in an atom

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3
Q

standing waves

A

vibrate in time but do not move in space

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4
Q

different sizes and shapes of standing wave

A

these are possible around the nucleus of an atom and are known as orbitals

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5
Q

orbitals

A

an area of space where there is a high probability of finding an electron

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6
Q

maximum capacity of an orbital

A

2 electrons

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7
Q

quantum numbers

A

define the energy of an electron and give information about its location within an atom

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8
Q

principle quantum number

A

n

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9
Q

n

A

describes the energy levels an electron is found in and is related to orbital size

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10
Q

possible values of n

A

n= 1,2,3 (1st shell, 2nd shell, 3rd shell)

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11
Q

angular momentum quantum number

A

l

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12
Q

l

A

describes the shape of the subshell / orbital

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13
Q

possible values of l

A

l=0 —> n-1

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14
Q

different shapes of orbitals are identified as

A

s(l=0) , p(l=1) , d(l=2) , f(l=3)

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15
Q

s orbital shape

A

spherical l=0

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16
Q

p orbital shape

A

dumbbell l=1

17
Q

d orbital shape

A

double dumbbell l=2

18
Q

magnetic quantum number

A

ml

19
Q

ml

A

describes the orientation in space time of the orbital

20
Q

possible values of ml

A

-l —> +l

21
Q

orbitals increase in energy from

A

s > p > d > f

22
Q

degenerate

A

equal in energy

23
Q

orbitals within a subshell (i.e. the same shape) are

A

degenerate

24
Q

spin magnetic quantum number

A

ms

25
Q

ms

A

describes the direction of electron spin

26
Q

spins in orbitals

A

two electrons in the same orbital must have opposite spins

27
Q

possible values of ms

A

+1/2 , -1/2